Chapter 14, Problem 99c
Americium-241 is used in smoke detectors. It has a first-order rate constant for radioactive decay of k = 1.6 * 10-3 yr-1. By contrast, iodine-125, which is used to test for thyroid functioning, has a rate constant for radioactive decay of k = 0.011 day-1. (c) How much of a 1.00-mg sample of each isotope remains after three half-lives?
Video transcript
The reaction 2 NO2¡2 NO + O2 has the rate constant k = 0.63 M- 1s - 1. (b) If the initial concentration of NO2 is 0.100 M, how would you determine how long it would take for the concentration to decrease to 0.025 M?
Consider two reactions. Reaction (1) has a constant halflife, whereas reaction (2) has a half-life that gets longer as the reaction proceeds. What can you conclude about the rate laws of these reactions from these observations?
Americium-241 is used in smoke detectors. It has a first-order rate constant for radioactive decay of k = 1.6 * 10-3 yr-1. By contrast, iodine-125, which is used to test for thyroid functioning, has a rate constant for radioactive decay of k = 0.011 day-1. (b) Which one decays at a faster rate?
The rate of a first-order reaction is followed by spectroscopy, monitoring the absorbance of a colored reactant at 520 nm. The reaction occurs in a 1.00-cm sample cell, and the only colored species in the reaction has an extinction coefficient of 5.60 * 103 M-1 cm-1 at 520 nm. (a) Calculate the initial concentration of the colored reactant if the absorbance is 0.605 at the beginning of the reaction.
The rate of a first-order reaction is followed by spectroscopy, monitoring the absorbance of a colored reactant at 520 nm. The reaction occurs in a 1.00-cm sample cell, and the only colored species in the reaction has an extinction coefficient of 5.60 * 103 M-1 cm-1 at 520 nm. (c) Calculate the half-life of the reaction.
The rate of a first-order reaction is followed by spectroscopy, monitoring the absorbance of a colored reactant at 520 nm. The reaction occurs in a 1.00-cm sample cell, and the only colored species in the reaction has an extinction coefficient of 5.60 * 103 M-1 cm-1 at 520 nm. (d) How long does it take for the absorbance to fall to 0.100?