Chapter 14, Problem 101a
The rate of a first-order reaction is followed by spectroscopy, monitoring the absorbance of a colored reactant at 520 nm. The reaction occurs in a 1.00-cm sample cell, and the only colored species in the reaction has an extinction coefficient of 5.60 * 103 M-1 cm-1 at 520 nm. (a) Calculate the initial concentration of the colored reactant if the absorbance is 0.605 at the beginning of the reaction.
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Consider two reactions. Reaction (1) has a constant halflife, whereas reaction (2) has a half-life that gets longer as the reaction proceeds. What can you conclude about the rate laws of these reactions from these observations?
Americium-241 is used in smoke detectors. It has a first-order rate constant for radioactive decay of k = 1.6 * 10-3 yr-1. By contrast, iodine-125, which is used to test for thyroid functioning, has a rate constant for radioactive decay of k = 0.011 day-1. (b) Which one decays at a faster rate?
Americium-241 is used in smoke detectors. It has a first-order rate constant for radioactive decay of k = 1.6 * 10-3 yr-1. By contrast, iodine-125, which is used to test for thyroid functioning, has a rate constant for radioactive decay of k = 0.011 day-1. (c) How much of a 1.00-mg sample of each isotope remains after three half-lives?
The rate of a first-order reaction is followed by spectroscopy, monitoring the absorbance of a colored reactant at 520 nm. The reaction occurs in a 1.00-cm sample cell, and the only colored species in the reaction has an extinction coefficient of 5.60 * 103 M-1 cm-1 at 520 nm. (c) Calculate the half-life of the reaction.
The rate of a first-order reaction is followed by spectroscopy, monitoring the absorbance of a colored reactant at 520 nm. The reaction occurs in a 1.00-cm sample cell, and the only colored species in the reaction has an extinction coefficient of 5.60 * 103 M-1 cm-1 at 520 nm. (d) How long does it take for the absorbance to fall to 0.100?
At 28 C, raw milk sours in 4.0 h but takes 48 h to sour in a refrigerator at 5 C. Estimate the activation energy in kJ>mol for the reaction that leads to the souring of milk.