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Ch.11 - Liquids and Intermolecular Forces

Chapter 11, Problem 84a

The following table gives the vapor pressure of hexafluorobenzene (C6F6) as a function of temperature: (a) By plotting these data in a suitable fashion, determine whether the Clausius–Clapeyron equation (Equation 11.1) is obeyed. If it is obeyed, use your plot to determine ∆Hvap for C6F6.

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Hi everyone. So here we have the value of favorite pressure of toy Elaine as a function of temperature shown in the following table. Were asked to determine if this data a basic classes copper own equation and if yes, calculate the entropy of vaporization for Toya lane. Recall that the classes chaperone equation is Ln. Of the second vapor pressure. About a friend vapor pressure equal to negative entropy of vaporization. Bye bye. R gas constant times one by a second temperature -1 by the first temperature. So we need to graph L N hmm versus one. So we need to first make our chart. Have L and P Left out in 31.2. Ln 51. End of 80.9. Ln 124. Oh N. And Ln 395. We get 3. 3. 1826. 4.39 22. 4. 0-8 to 5. 5. 5.97 8886. And then for one of our batik We have one by by 300 What? About about 310. What about about 320. Want to buy about one. What? About about 350 one. About about 360. You get 0. 0.0032 - six. 0.00 0. 303 0. 0. 0.00 778. Can I grab this? The graph is going to be linear. It's gonna look like this so the data obeys the Closius chaperon equation. It was slow of this graph is gonna be equal to the negative of the entropy of vaporization. What about art? The interview vaporization equals negative M times R. And M was negative. 4568 0.6 from the graph. In the unit of slope mm It was the delta Y divided by delta X. This gives us one over K. Two the naked one power. Which gives us K. For the entropy of vaporization we get negative - 0.6 oven Times 8. promote, I'm Calvin. We get 37, 183. jules promote the entropy of vaporization. People's 38 promote. Thanks for watching my video and I hope it was helpful
Related Practice
Textbook Question

Use the normal boiling points propane (C3H8) -42.1 °C butane (C4H10) -0.5 °C pentane (C5H12) 36.1 °C hexane (C6H14) 68.7 °C heptane (C7H16) 98.4 °C to estimate the normal boiling point of octane (C8H18). Explain the trend in the boiling points.

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Textbook Question

(a) When you exercise vigorously, you sweat. How does this help your body cool?

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Textbook Question

(b) A flask of water is connected to a vacuum pump. A few moments after the pump is turned on, the water begins to boil. After a few minutes, the water begins to freeze. Explain why these processes occur.

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Textbook Question

Suppose the vapor pressure of a substance is measured at two different temperatures. (a) By using the Clausius–Clapeyron equation (Equation 11.1) derive the following relationship between the vapor pressures, P1 and P2, and the absolute temperatures at which they were measured, T1 and T2: (b) Gasoline is a mixture of hydrocarbons, a component of which is octane (CH3CH2CH2CH2CH2CH2CH2CH3). Octane has a vapor pressure of 13.95 torr at 25 °C and a vapor pressure of 144.78 torr at 75 °C. Use these data and the equation in part (a) to calculate the heat of vaporization of octane. (c) By using the equation in part (a) and the data given in part (b), calculate the normal boiling point of octane. Compare your answer to the one you obtained from Exercise 11.81. (d) Calculate the vapor pressure of octane at - 30 °C.

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Textbook Question
The following data present the temperatures at which certain vapor pressures are achieved for dichloromethane (CH2Cl2) and methyl iodide (CH3I): (c) The order of volatility of these two substances changes as the temperature is increased. What quantity must be different for the two substances for this phenom- enon to occur?
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Textbook Question

Naphthalene (C10H8) is the main ingredient in traditional mothballs. Its normal melting point is 81 °C, its normal boiling point is 218 °C, and its triple point is 80 °C at 1000 Pa. Using the data, construct a phase diagram for naphthalene, labeling all the regions of your diagram.

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