The ionic liquid (bmim+)(PF6−) has a melting point of 10°C and a surface tension of approximately 4.5×10−2 J/m2 at room temperature. By comparison, the melting point of H2O is 0°C and its surface tension is 7.3×10−2 J/m2 at room temperature. What is the most plausible explanation for the higher surface tension of water?
i. hydrogen bonding interactions are stronger than ion–ion interactions.
ii. Surface tension increases as molecules become smaller and more symmetric because the number of neighboring molecules in the liquid state increases.
iii. As the molecules become smaller, they can escape into the gas phases more easily, leading to an increase in surface tension.