Li-ion batteries used in automobiles typically use a LiMn2O4 cathode in place of the LiCoO2 cathode found in most Li-ion batteries. (b) Which material has a higher percentage of lithium? Does this help to explain why batteries made with LiMn2O4 cathodes deliver less power on discharging?
Ch.20 - Electrochemistry
Chapter 20, Problem 81b
(b) Using the standard reduction potentials in Appendix E, calculate the standard voltage generated by the hydrogen fuel cell in acidic solution.
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Identify the half-reactions involved in the hydrogen fuel cell. In an acidic solution, the reactions are: the oxidation of hydrogen (H₂) and the reduction of oxygen (O₂).
Write the half-reactions: Oxidation half-reaction: H₂ → 2H⁺ + 2e⁻. Reduction half-reaction: O₂ + 4H⁺ + 4e⁻ → 2H₂O.
Look up the standard reduction potentials (E°) for each half-reaction in Appendix E. Note that the standard reduction potential for the oxidation reaction will be the negative of the value listed, as it is written as a reduction.
Calculate the standard cell potential (E°cell) using the formula: E°cell = E°(cathode) - E°(anode). Substitute the values from the standard reduction potentials you found.
Ensure that the overall cell reaction is balanced in terms of both mass and charge, and verify that the calculated E°cell is positive, indicating a spontaneous reaction under standard conditions.
Related Practice
Textbook Question
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Textbook Question
Li-ion batteries used in automobiles typically use a LiMn2O4 cathode in place of the LiCoO2 cathode found in most Li-ion batteries. (c) In a battery that uses a LiCoO2 cathode, approximately 50% of the lithium migrates from the cathode to the anode on charging. In a battery that uses a LiMn2O4 cathode, what fraction of the lithium in LiMn2O4 would need to migrate out of the cathode to deliver the same amount of lithium to the graphite anode?
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Textbook Question
(a) Which reaction is spontaneous in the hydrogen fuel cell: hydrogen gas plus oxygen gas makes water, or water makes hydrogen gas plus oxygen gas?
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Textbook Question
(b) Can the “fuel” of a fuel cell be a solid?
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Open Question
(a) Write the anode and cathode reactions that cause the corrosion of iron metal to aqueous iron(II).
Open Question
(b) When the Statue of Liberty was refurbished, Teflon spacers were placed between the iron skeleton and the copper metal on the surface of the statue. What role do these spacers play?