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Ch.14 - Chemical Kinetics

Chapter 14, Problem 51b

(b) Does the rate constant for a reaction generally increase or decrease with an increase in reaction temperature?

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Hi everyone for this problem. We're being asked how does the rate constant change with increasing activation energy? So we're dealing with rate constant and activation energy. So we're going to want to write out the Iranians equation to solve this problem. And the Iranians equation, is this okay? Where K represents our rate constant A. Is our pre exponential factor, E. A. Is activation energy and our times T. Is average kinetic energy. So the two variables that we're interested here is K. Our rate constant and E. A. R. Activation energy. So as you can see here they have an inverse relationship. So that means what happens to one, the opposite will happen to the other. And in the problem we're being asked, how does the rate constant change with increasing activation energy? So if our activation energy is increasing and we have an inverse relationship between the two variables, that means our rate constant is going to decrease. Okay. And so the answer to this problem is as the activation energy increases, the rate constant K decreases. That's the answer to this problem. I hope this was helpful
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