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Ch.10 - Chemical Bonding II: Molecular Shapes & Valence Bond Theory
Chapter 10, Problem 88b

The structure of acetylsalicylic acid (aspirin) is shown here. How many sigma bonds?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Sigma Bonds

Sigma bonds are the strongest type of covalent bond formed by the head-on overlap of atomic orbitals. Each sigma bond allows for free rotation around the bond axis and is characterized by a cylindrical symmetry around the bond. In organic molecules, sigma bonds are typically formed between carbon and other atoms, such as hydrogen or oxygen.
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Molecular Structure

The molecular structure refers to the arrangement of atoms within a molecule, including the types of bonds and the spatial orientation of these atoms. Understanding the molecular structure is crucial for determining the number of sigma bonds, as it helps visualize how atoms are connected and the types of orbitals involved in bonding.
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Counting Bonds in Organic Compounds

Counting bonds in organic compounds involves identifying all the covalent bonds present in the molecular structure. Each single bond represents one sigma bond, while double and triple bonds consist of one sigma bond and one or two pi bonds, respectively. This process is essential for understanding the bonding framework of molecules like acetylsalicylic acid.
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Related Practice
Open Question
For each compound, draw the Lewis structure, determine the geometry using VSEPR theory, determine whether the molecule is polar, identify the hybridization of all interior atoms, and make a sketch of the molecule according to valence bond theory, showing orbital overlap. a. IF5 b. CH2CHCH3 c. CH3SH
Textbook Question

The genetic code is based on four different bases with the structures shown here. Assign a geometry and hybridization to each interior atom in these four bases. d. guanine

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Textbook Question

The structure of acetylsalicylic acid (aspirin) is shown here. How many π bonds are present in acetylsalicylic acid?

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Textbook Question

Most vitamins can be classified as either fat soluble, which results in their tendency to accumulate in the body (so that taking too much can be harmful), or water soluble, which results in their tendency to be quickly eliminated from the body in urine. Examine the structural formulas and space-filling models of these vitamins and determine whether each one is fat soluble (mostly nonpolar) or water soluble (mostly polar). (a) vitamin C

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Textbook Question

Most vitamins can be classified as either fat soluble, which results in their tendency to accumulate in the body (so that taking too much can be harmful), or water soluble, which results in their tendency to be quickly eliminated from the body in urine. Examine the structural formulas and space-filling models of these vitamins and determine whether each one is fat soluble (mostly nonpolar) or water soluble (mostly polar). (c) niacin (vitamin B3)

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Textbook Question

Water does not easily remove grease from dishes or hands because grease is nonpolar and water is polar. The addition of soap to water, however, allows the grease to dissolve. Study the structure of sodium stearate (a soap) and describe how it works.

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