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Ch.10 - Chemical Bonding II: Molecular Shapes & Valence Bond Theory
Chapter 10, Problem 86d

The genetic code is based on four different bases with the structures shown here. Assign a geometry and hybridization to each interior atom in these four bases. d. guanine
Chemical structure of guanine with labeled atoms for hybridization analysis.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Hybridization

Hybridization is the concept of mixing atomic orbitals to form new hybrid orbitals that can accommodate the bonding requirements of atoms in a molecule. In guanine, for example, carbon atoms typically exhibit sp2 hybridization, allowing for the formation of planar structures with double bonds, while nitrogen atoms may show sp3 hybridization, accommodating lone pairs and bonding.
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Molecular Geometry

Molecular geometry refers to the three-dimensional arrangement of atoms within a molecule. The geometry is determined by the hybridization of the central atom and the number of bonds and lone pairs surrounding it. For guanine, the arrangement of atoms leads to a specific geometry that influences its interactions and functions in biological systems.
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Resonance Structures

Resonance structures are different ways of drawing a molecule that represent the same arrangement of atoms but differ in the distribution of electrons. In guanine, resonance is important for understanding the delocalization of electrons in the aromatic ring and the stability of the molecule, which is crucial for its role in the genetic code.
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Related Practice
Textbook Question

Draw an energy diagram for HCl. Predict the bond order and make a sketch of the lowest energy bonding molecular orbital.

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Open Question
For each compound, draw the Lewis structure, determine the geometry using VSEPR theory, determine whether the molecule is polar, identify the hybridization of all interior atoms, and make a sketch of the molecule according to valence bond theory showing orbital overlap: a. COF2 (carbon is the central atom) b. S2Cl2 (ClSSCl) c. SF4.
Open Question
For each compound, draw the Lewis structure, determine the geometry using VSEPR theory, determine whether the molecule is polar, identify the hybridization of all interior atoms, and make a sketch of the molecule according to valence bond theory, showing orbital overlap. a. IF5 b. CH2CHCH3 c. CH3SH
Textbook Question

The structure of acetylsalicylic acid (aspirin) is shown here. How many π bonds are present in acetylsalicylic acid?

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Textbook Question

The structure of acetylsalicylic acid (aspirin) is shown here. How many sigma bonds?

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Textbook Question

Most vitamins can be classified as either fat soluble, which results in their tendency to accumulate in the body (so that taking too much can be harmful), or water soluble, which results in their tendency to be quickly eliminated from the body in urine. Examine the structural formulas and space-filling models of these vitamins and determine whether each one is fat soluble (mostly nonpolar) or water soluble (mostly polar). (a) vitamin C

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