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Ch 20: The Second Law of Thermodynamics
Chapter 20, Problem 20

A certain brand of freezer is advertised to use 730 kW•h of energy per year. (c) What is the theoretical maximum amount of ice this freezer could make in an hour, starting with water at 20.0°C?

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1
Calculate the energy required to cool water from 20.0°C to 0°C using the specific heat capacity of water. Use the formula: Q = mcΔT, where m is the mass of water, c is the specific heat capacity of water (approximately 4.18 J/g°C), and ΔT is the change in temperature.
Calculate the energy required to freeze the water at 0°C into ice using the latent heat of fusion of water. Use the formula: Q = mL, where m is the mass of water and L is the latent heat of fusion of water (approximately 334 J/g).
Add the energy calculated in step 1 and step 2 to find the total energy required to turn water at 20.0°C into ice.
Convert the freezer's energy usage from kW•h to Joules to match the units used in the calculations above. Use the conversion factor: 1 kW•h = 3.6 × 10^6 J.
Divide the freezer's hourly energy usage in Joules (from step 4) by the total energy required per gram of ice (from step 3) to find the theoretical maximum mass of ice the freezer can produce in an hour.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Energy Transfer

Energy transfer refers to the movement of energy from one system to another. In the context of the freezer, it involves the conversion of electrical energy into thermal energy, which is used to lower the temperature of water to freeze it. Understanding this concept is crucial for calculating how much energy is required to change the state of water from liquid to solid.
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Overview of Heat Transfer

Latent Heat of Fusion

Latent heat of fusion is the amount of energy required to change a substance from solid to liquid or vice versa without changing its temperature. For water, this value is approximately 334 kJ/kg. This concept is essential for determining how much energy is needed to freeze water into ice, as it directly influences the amount of ice that can be produced by the freezer.
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Specific Heat Capacity

Specific heat capacity is the amount of heat required to raise the temperature of a unit mass of a substance by one degree Celsius. For water, this value is about 4.18 kJ/kg°C. In this scenario, it is important to calculate the energy needed to cool water from 20.0°C to 0°C before it can freeze, which is a necessary step in determining the total ice production capacity of the freezer.
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Related Practice
Textbook Question
The coefficient of performance K = H/P is a dimensionless quantity. Its value is independent of the units used for H and P, as long as the same units, such as watts, are used for both quantities. However, it is common practice to express H in Btu/h and P in watts. When these mixed units are used, the ratio H/P is called the energy efficiency ratio (EER). If a room air conditioner has K = 3.0, what is its EER?
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Textbook Question
A refrigerator has a coefficient of performance of 2.25, runs on an input of 135 W of electrical power, and keeps its inside compartment at 5°C. If you put a dozen 1.0-L plastic bottles of water at 31°C into this refrigerator, how long will it take for them to be cooled down to 5°C? (Ignore any heat that leaves the plastic.)
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Textbook Question
A certain brand of freezer is advertised to use 730 kW•h of energy per year. (a) Assuming the freezer operates for 5 hours each day, how much power does it require while operating?
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Textbook Question
A box is separated by a partition into two parts of equal volume. The left side of the box contains 500 molecules of nitrogen gas; the right side contains 100 molecules of oxygen gas. The two gases are at the same temperature. The partition is punctured, and equilibrium is eventually attained. Assume that the volume of the box is large enough for each gas to undergo a free expansion and not change temperature. (a) On average, how many molecules of each type will there be in either half of the box?
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Textbook Question
CALC A lonely party balloon with a volume of 2.40 L and containing 0.100 mol of air is left behind to drift in the temporarily uninhabited and depressurized International Space Station. Sunlight coming through a porthole heats and explodes the balloon, causing the air in it to undergo a free expansion into the empty station, whose total volume is 425 m^3. Calculate the entropy change of the air during the expansion.
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Textbook Question
A Carnot engine is operated between two heat reservoirs at temperatures of 520 K and 300 K. (a) If the engine receives 6.45 kJ of heat energy from the reservoir at 520 K in each cycle, how many joules per cycle does it discard to the reservoir at 300 K?
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