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Ch 19: The First Law of Thermodynamics
Chapter 19, Problem 19

The pV-diagram in Fig. E19.13 shows a process abc involving 0.450 mol of an ideal gas.pV-diagram showing process abc for 0.450 mol of ideal gas in thermodynamics.
(c) How much heat had to be added during the process to increase the internal energy of the gas by 15,000 J?pV-diagram illustrating process abc with points a, b, and c for an ideal gas.

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1
Identify the initial and final states of the gas in the pV-diagram. The process involves states a, b, and c.
Calculate the work done by the gas during the process. For each segment (a to b and b to c), use the formula for work done in a pV-diagram: W = P * ΔV for isobaric processes and W = 0 for isochoric processes.
Determine the change in internal energy (ΔU) of the gas. Given that ΔU = 15,000 J.
Use the first law of thermodynamics, which states ΔU = Q - W, to find the heat added (Q) during the process. Rearrange the equation to solve for Q: Q = ΔU + W.
Substitute the values of ΔU and W into the equation to find the heat added (Q).

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Textbook Question
A cylinder contains 0.0100 mol of helium at T = 27.0°C. (a) How much heat is needed to raise the temperature to 67.0°C while keeping the volume constant? Draw a pV-diagram for this process. (b) If instead the pressure of the helium is kept constant, how much heat is needed to raise the temperature from 27.0°C to 67.0°C? Draw a pV-diagram for this process. (c) What accounts for the difference between your answers to parts (a) and (b)? In which case is more heat required? What becomes of the additional heat? (d) If the gas is ideal, what is the change in its internal energy in part (a)? In part (b)? How do the two answers compare? Why?
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