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Ch 19: The First Law of Thermodynamics
Chapter 19, Problem 19

On a warm summer day, a large mass of air (atmospheric pressure 1.01 * 10^5 Pa) is heated by the ground to 26.0°C and then begins to rise through the cooler surrounding air. (This can be treated approximately as an adiabatic process; why?) Calculate the temperature of the air mass when it has risen to a level at which atmospheric pressure is only 0.850 * 105 Pa. Assume that air is an ideal gas, with g = 1.40. (This rate of cooling for dry, rising air, corresponding to roughly 1 C° per 100 m of altitude, is called the dry adiabatic lapse rate.)

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Identify the initial conditions and constants: initial pressure (P1) = 1.01 * 10^5 Pa, initial temperature (T1) = 26.0°C (convert to Kelvin by adding 273.15), final pressure (P2) = 0.850 * 10^5 Pa, and the adiabatic index (γ) = 1.40.
Understand that the process is adiabatic, meaning no heat is transferred to or from the air mass. This is a reasonable assumption because the process of rising air happens relatively quickly, and the heat exchange with the surroundings can be negligible.
Use the adiabatic process equation for an ideal gas, which relates pressure and temperature: \( T2 = T1 \times \left(\frac{P2}{P1}\right)^{\frac{\gamma - 1}{\gamma}} \). This equation comes from combining the ideal gas law with the adiabatic condition (PV^γ = constant).
Substitute the known values into the equation to find the final temperature (T2) in Kelvin. Make sure to use the correct units and convert temperatures to Kelvin where necessary.
If desired, convert the final temperature back to Celsius by subtracting 273.15 from the Kelvin result to relate it to common temperature scales.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Adiabatic Process

An adiabatic process is one in which no heat is exchanged with the surroundings. In the context of rising air, as the air mass ascends, it expands due to lower pressure, causing it to cool without gaining or losing heat. This is significant in meteorology, as it helps explain how temperature changes in the atmosphere occur without heat transfer.
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Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, and temperature of an ideal gas through the equation PV = nRT. In this scenario, the air mass can be approximated as an ideal gas, allowing us to use this relationship to calculate changes in temperature as the air rises and pressure decreases. This simplification is crucial for understanding the behavior of gases under varying conditions.
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Dry Adiabatic Lapse Rate

The dry adiabatic lapse rate is the rate at which the temperature of a rising dry air parcel decreases with altitude, approximately 1°C per 100 meters. This concept is essential for predicting how the temperature of the air mass will change as it ascends through the atmosphere, providing a basis for calculating the final temperature at a given pressure.
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Related Practice
Textbook Question
A monatomic ideal gas that is initially at 1.50 * 10^5 Pa and has a volume of 0.0800 m^3 is compressed adiabatically to a volume of 0.0400 m^3. (c) What is the ratio of the final temperature of the gas to its initial temperature? Is the gas heated or cooled by this compression?
806
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Textbook Question
The engine of a Ferrari F355 F1 sports car takes in air at 20.0°C and 1.00 atm and compresses it adiabatically to 0.0900 times the original volume. The air may be treated as an ideal gas with g = 1.40. (b) Find the final temperature and pressure.
505
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Textbook Question
A player bounces a basketball on the floor, compressing it to 80.0% of its original volume. The air (assume it is essentially N2 gas) inside the ball is originally at 20.0°C and 2.00 atm. The ball's inside diameter is 23.9 cm. (a) What temperature does the air in the ball reach at its maximum compression? Assume the compression is adiabatic and treat the gas as ideal.
779
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Textbook Question
A cylinder contains 0.100 mol of an ideal monatomic gas. Initially the gas is at 1.00 * 10^5 Pa and occupies a volume of 2.50 * 10^-3 m^3. (b) If the gas is allowed to expand to twice the initial volume, find the final temperature (in kelvins) and pressure of the gas if the expansion is (i) isothermal; (ii) isobaric; (iii) adiabatic.
417
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Textbook Question
A cylinder contains 0.100 mol of an ideal monatomic gas. Initially the gas is at 1.00 * 10^5 Pa and occupies a volume of 2.50 * 10^-3 m^3. (b) If the gas is allowed to expand to twice the initial volume, find the final temperature (in kelvins) and pressure of the gas if the expansion is (i) isothermal; (ii) isobaric; (iii) adiabatic.
775
views
Textbook Question
A cylinder contains 0.100 mol of an ideal monatomic gas. Initially the gas is at 1.00 * 10^5 Pa and occupies a volume of 2.50 * 10^-3 m^3. (b) If the gas is allowed to expand to twice the initial volume, find the final temperature (in kelvins) and pressure of the gas if the expansion is (i) isothermal; (ii) isobaric; (iii) adiabatic.
507
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