2.0 mol of helium at 280℃ undergo an isobaric process in which the helium entropy increases by 35 J/K. What is the final temperature of the gas?
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Identify the initial temperature in Kelvin. Since the given temperature is in Celsius, convert it to Kelvin by adding 273.15 to the Celsius temperature.
Use the formula for entropy change in an isobaric process, which is \(\Delta S = nC_P\ln\frac{T_f}{T_i}\), where \(\Delta S\) is the entropy change, \(n\) is the number of moles, \(C_P\) is the molar heat capacity at constant pressure, and \(T_i\) and \(T_f\) are the initial and final temperatures in Kelvin, respectively.
For helium, a monatomic ideal gas, the molar heat capacity at constant pressure, \(C_P\), can be calculated using the relation \(C_P = \frac{5}{2}R\), where \(R\) is the universal gas constant approximately equal to 8.314 J/(mol·K).
Rearrange the entropy change formula to solve for the final temperature \(T_f\). This can be done by exponentiating both sides to get rid of the natural logarithm, resulting in \(T_f = T_i e^{\frac{\Delta S}{nC_P}}\).
Substitute the values for \(\Delta S\), \(n\), \(C_P\), and \(T_i\) into the rearranged formula to find \(T_f\), the final temperature in Kelvin. Convert this back to Celsius if required by subtracting 273.15 from the Kelvin temperature.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Isobaric Process
An isobaric process is a thermodynamic process in which the pressure remains constant while the volume and temperature of the gas may change. In such processes, the heat added to the system results in work done by the gas as it expands. This concept is crucial for understanding how gases behave under constant pressure conditions.
Heat Equations for Isobaric & Isovolumetric Processes
Entropy
Entropy is a measure of the disorder or randomness in a system, often associated with the amount of energy unavailable for doing work. In thermodynamics, an increase in entropy indicates that the system has absorbed heat or undergone a change that increases its disorder. Understanding entropy is essential for analyzing energy transfers and transformations in thermodynamic processes.
The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of an ideal gas through the equation PV = nRT. This law is fundamental in thermodynamics and allows for the calculation of one property of a gas when the others are known. In this problem, it can be used to find the final temperature of helium after the isobaric process.