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Ch 20: The Micro/Macro Connection
Chapter 20, Problem 20

2.0 mol of helium at 280℃ undergo an isobaric process in which the helium entropy increases by 35 J/K. What is the final temperature of the gas?

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1
Identify the initial temperature in Kelvin. Since the given temperature is in Celsius, convert it to Kelvin by adding 273.15 to the Celsius temperature.
Use the formula for entropy change in an isobaric process, which is \(\Delta S = nC_P\ln\frac{T_f}{T_i}\), where \(\Delta S\) is the entropy change, \(n\) is the number of moles, \(C_P\) is the molar heat capacity at constant pressure, and \(T_i\) and \(T_f\) are the initial and final temperatures in Kelvin, respectively.
For helium, a monatomic ideal gas, the molar heat capacity at constant pressure, \(C_P\), can be calculated using the relation \(C_P = \frac{5}{2}R\), where \(R\) is the universal gas constant approximately equal to 8.314 J/(mol·K).
Rearrange the entropy change formula to solve for the final temperature \(T_f\). This can be done by exponentiating both sides to get rid of the natural logarithm, resulting in \(T_f = T_i e^{\frac{\Delta S}{nC_P}}\).
Substitute the values for \(\Delta S\), \(n\), \(C_P\), and \(T_i\) into the rearranged formula to find \(T_f\), the final temperature in Kelvin. Convert this back to Celsius if required by subtracting 273.15 from the Kelvin temperature.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Isobaric Process

An isobaric process is a thermodynamic process in which the pressure remains constant while the volume and temperature of the gas may change. In such processes, the heat added to the system results in work done by the gas as it expands. This concept is crucial for understanding how gases behave under constant pressure conditions.
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Entropy

Entropy is a measure of the disorder or randomness in a system, often associated with the amount of energy unavailable for doing work. In thermodynamics, an increase in entropy indicates that the system has absorbed heat or undergone a change that increases its disorder. Understanding entropy is essential for analyzing energy transfers and transformations in thermodynamic processes.
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Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of an ideal gas through the equation PV = nRT. This law is fundamental in thermodynamics and allows for the calculation of one property of a gas when the others are known. In this problem, it can be used to find the final temperature of helium after the isobaric process.
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Related Practice
Textbook Question
The molecules in a six-particle gas have velocities v₁ = (20î ─ 30ĵ) m/s v₂ = (40î + 70ĵ) m/s v₃ = (─80î + 20ĵ) m/s v₄ = 30î m/s v₅ = (40î ─ 40ĵ) m/s v₆ = (─50î ─ 20ĵ) m/s Calculate (a) →vₐᵥ₉ , (b) vₐᵥ₉, and (c) vᵣₘₛ.
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Textbook Question
A 75 g ice cube at 0℃ is placed on a very large table at 20℃. You can assume that the temperature of the table does not change. As the ice cube melts and then comes to thermal equilibrium, what are the entropy changes of (a) the water, (b) the table, and (c) the universe?
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Textbook Question
What is the entropy change of the nitrogen if 250 mL of liquid nitrogen boils away and then warms to 20℃ at constant pressure? The density of liquid nitrogen is 810 kg/m³.
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Textbook Question
A thin partition divides a container of volume V into two parts. One side contains nA moles of gas A in a fraction fA of the container; that is, VA = fAV. The other side contains nB moles of a different gas B at the same temperature in a fraction fB of the container. The partition is removed, allowing the gases to mix. Find an expression for the change of entropy. This is called the ,entropy of mixing.
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Textbook Question
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Textbook Question
Your calculator can't handle enormous exponents, but we can make sense of large powers of e by converting them to large powers of 10. If we write e = 10^α, then e^β = (10^α)^β = 10^αβ. b. What is the multiplicity of a macrostate with entropy S = 1.0 J/K? Give your answer as a power of 10.
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