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Ch.15 Aldehydes and Ketones
Chapter 15, Problem 15.1

Which of the following molecules contain aldehyde or ketone functional groups? You may want to refer to Table 15.1, Table 12.1, and Figure 15.3 to help in your identification. Copy the formulas and circle these functional groups.


a. <IMAGE> Prostaglandin E₁
b. <IMAGE> Testosterone (a male hormone)
c. <IMAGE> Vanillin (a flavoring agent)
d. C₄H₉COCH₃
e. C₄H₉CHO

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1
Identify the structural features of aldehydes and ketones: Aldehydes have a carbonyl group (C=O) bonded to at least one hydrogen atom, while ketones have a carbonyl group bonded to two carbon atoms.
Examine each molecule or formula to locate the carbonyl group (C=O).
For each molecule, determine if the carbonyl group is bonded to a hydrogen (indicating an aldehyde) or to two carbons (indicating a ketone).
For the given chemical formulas, C₄H₉COCH₃ and C₄H₉CHO, identify the functional groups by analyzing the position of the carbonyl group relative to other atoms.
Circle the identified aldehyde or ketone functional groups in the molecular structures or formulas.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Functional Groups

Functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. In organic chemistry, common functional groups include aldehydes and ketones, which contain carbonyl groups (C=O) but differ in their structure. Aldehydes have the carbonyl group at the end of the carbon chain, while ketones have it within the chain.
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Aldehydes

Aldehydes are organic compounds that contain a carbonyl group (C=O) bonded to at least one hydrogen atom. This structure gives aldehydes unique properties, such as their reactivity and ability to participate in various chemical reactions, including oxidation. Common examples include formaldehyde and benzaldehyde, which are used in various industrial and laboratory applications.
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Ketones

Ketones are a class of organic compounds characterized by a carbonyl group (C=O) flanked by two carbon atoms. This structure makes ketones distinct from aldehydes, as they do not have a hydrogen atom directly attached to the carbonyl carbon. Ketones are commonly found in solvents and are important in biological processes, with acetone being a well-known example.
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