In 1911, Ernest Rutherford's gold foil experiment led to the discovery of the positively charged nucleus within an atom. Now, he was assisted by fellow chemists Hans Geiger and Ernest Marsden. And because they had such a big role in this experiment, it's sometimes also referred to as the Geiger Marsden experiment. Just remember that this experiment is known by both of these names: the Rutherford gold experiment as well as the Geiger Marsden experiment. The experimental setup is a thin sheet of gold foil. Here we have our gold foil right here, bombarded with alpha particles emitting from a radioactive element.
The alpha particle itself is a radioactive particle consisting of 2 protons and 2 neutrons. If we were to write out its elemental symbol, we would say it has 2 protons, which means its atomic number is 2. Its mass number, the total of neutrons and protons together, would be 4, and we would use the alpha symbol. Here we're not talking about any electrons involved; neutrons are neutral, protons are positive, so the overall charge would be 2+. An element on the periodic table also has an atomic number of 2, and that would be helium. So another way of depicting this alpha particle is 42He+2.
The radioactive element is encased within this lead box with one part of it open which emits the alpha particles. The radioactive element itself is usually iridium, and again it's encased within this lead container. Around this gold foil or gold sheet, we're going to have what's called our detecting screen. This screen right here has a small slit which allows for the passage of the alpha particles to enter. What happens here is that the alpha particles emitted from the iridium would go through the gold foil and hit the back of the detecting screen. However, we also found that some of these positively charged alpha particles would be striking something in the center of the gold foil. This would cause some of these alpha particles to change trajectories; they wouldn't go straight through it. They would hit different parts of the detecting sheet, which surprised our chemists. In some cases, the alpha particle would shoot out towards the gold foil and come right back towards the radioactive source.
From this, Rutherford was able to come up with his three postulates. The postulates were, firstly, that the proton and neutron are located in the nucleus, which lies at the center of the atom. Rutherford was also able to determine that although incredibly small, the nucleus comprised most of the mass of the atom. Finally, Rutherford figured out that surrounding the dense positively charged nucleus is a cloud of electrons. From the gold foil experiment, we were able to come up with these three postulates in the case of Rutherford and his assistants. These are seen as common ideas today, but back then, they were pretty groundbreaking and went against many laws that chemists considered at the time. This kind of turned all that on its head and challenged a lot of the conceptions that chemists had at that time. Through the actions of Rutherford, Geiger, and Marsden, we have a better understanding of the atom.