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Ch.7 - Thermochemistry
Chapter 7, Problem 73

Two substances, A and B, initially at different temperatures, come into contact and reach thermal equilibrium. The mass of substance A is 6.15 g and its initial temperature is 20.5 °C. The mass of substance B is 25.2 g and its initial temperature is 52.7 °C. The final temperature of both substances at thermal equilibrium is 46.7 °C. If the specific heat capacity of substance B is 1.17 J/g•°C, what is the specific heat capacity of substance A?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Thermal Equilibrium

Thermal equilibrium occurs when two substances at different temperatures come into contact and exchange heat until they reach the same temperature. At this point, the heat lost by the hotter substance equals the heat gained by the cooler substance, resulting in no net heat flow between them. This principle is fundamental in calorimetry and helps in understanding heat transfer in physical systems.
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Specific Heat Capacity

Specific heat capacity is the amount of heat required to raise the temperature of one gram of a substance by one degree Celsius. It is a material-specific property that indicates how much energy a substance can store or release as its temperature changes. Knowing the specific heat capacities of substances allows for calculations involving heat transfer and temperature changes in thermal processes.
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Heat Transfer Equation

The heat transfer equation, often expressed as Q = mcΔT, relates the heat (Q) absorbed or released by a substance to its mass (m), specific heat capacity (c), and the change in temperature (ΔT). This equation is crucial for solving problems involving thermal equilibrium, as it allows for the calculation of unknown variables, such as specific heat capacity, when the other parameters are known.
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Related Practice
Textbook Question

A 32.5-g iron rod, initially at 22.7 °C, is submerged into an unknown mass of water at 63.2 °C, in an insulated container. The final temperature of the mixture upon reaching thermal equilibrium is 59.5 °C. What is the mass of the water?

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Textbook Question

A 31.1-g wafer of pure gold, initially at 69.3 °C, is submerged into 64.2 g of water at 27.8 °C in an insulated container. What is the final temperature of both substances at thermal equilibrium?

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Textbook Question

A 2.85-g lead weight, initially at 10.3 °C, is submerged in 7.55 g of water at 52.3 °C in an insulated container. What is the final temperature of both substances at thermal equilibrium?

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Textbook Question

Exactly 1.5 g of a fuel burns under conditions of constant pressure and then again under conditions of constant volume. In measurement A the reaction produces 25.9 kJ of heat, and in measurement B the reaction produces 23.3 kJ of heat. Which measurement (A or B) corresponds to conditions of constant pressure? Explain.

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Textbook Question

When 1.03 g of biphenyl (C12H10) undergoes combustion in a bomb calorimeter, the temperature rises from 24.2 °C to 2931.4 °C. Find ΔErxn for the combustion of biphenyl in kJ>mol biphenyl. The heat capacity of the bomb calorimeter, determined in a separate experiment, is 5.86 kJ/°C.

Textbook Question

Zinc metal reacts with hydrochloric acid according to the balanced equation: Zn(s) + 2 HCl(aq) → ZnCl2(aq) + H2(g) When 0.103 g of Zn(s) is combined with enough HCl to make 50.0 mL of solution in a coffee-cup calorimeter, all of the zinc reacts, raising the temperature of the solution from 22.5 °C to 23.7 °C. Find ΔHrxn for this reaction as written. (Use 1.0 g/mL for the density of the solution and 4.18 J/g•°C as the specific heat capacity.)

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