Chapter 19, Problem 87b
Determine the sign of ΔSsys for each process. b. water freezing
Video transcript
Consider the reaction: 2 NO( g) + O2( g) ⇌ 2 NO2( g) The following data show the equilibrium constant for this reaction measured at several different temperatures. Use the data to find ΔH° rxn and ΔS°rxn for the reaction.
A reaction has an equilibrium constant of 8.5⨉103 at 298 K. At 755 K, the equilibrium constant is 55.2. Find ΔH°rxn for the reaction.
Determine the sign of ΔSsys for each process. a. water boiling
Nitrogen dioxide, a pollutant in the atmosphere, can combine with water to form nitric acid. One of the possible reactions is shown here. Calculate ΔG° and K p for this reaction at 25 °C and comment on the spontaneity of the reaction. 3 NO2(g) + H2O(l )→ 2 HNO3(aq) + NO(g)
Consider this reaction occurring at 298 K: N2O(g) + NO2(g) ⇌ 3 NO(g) a. Show that the reaction is not spontaneous under standard conditions by calculating ΔG°rxn.
Consider this reaction occurring at 298 K: N2O( g) + NO2( g) ⇌ 3 NO( g) b. If a reaction mixture contains only N2O and NO2 at partial pressures of 1.0 atm each, the reaction will be spontaneous until some NO forms in the mixture. What maximum partial pressure of NO builds up before the reaction ceases to be spontaneous?