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Ch.16 - Chemical Equilibrium
Chapter 16, Problem 83

Consider the exothermic reaction: C2H4(g) + Cl2(g) ⇌ C2H4Cl2(g) If you were trying to maximize the amount of C2H4Cl2 produced, which tactic might you try? Assume that the reaction mixture reaches equilibrium. a. increasing the reaction volume b. removing C2H4Cl2 from the reaction mixture as it forms c. lowering the reaction temperature d. adding Cl2

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Le Chatelier's Principle

Le Chatelier's Principle states that if a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium shifts to counteract the change. This principle helps predict how a system at equilibrium will respond to changes in concentration, temperature, or pressure, allowing for strategies to maximize product formation.
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Le Chatelier's Principle

Exothermic Reactions

Exothermic reactions release heat as they proceed, resulting in a decrease in the system's internal energy. For exothermic reactions, lowering the temperature generally favors the formation of products, as the system shifts to produce more heat to counteract the temperature change, thus increasing the yield of products like C2H4Cl2.
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Endothermic & Exothermic Reactions

Equilibrium Constant (K)

The equilibrium constant (K) quantifies the ratio of the concentrations of products to reactants at equilibrium for a given reaction at a specific temperature. Changes in concentration or pressure can shift the equilibrium position, affecting the amounts of reactants and products present, which is crucial for determining the best tactic to maximize C2H4Cl2 production.
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Related Practice
Textbook Question

Coal can be used to generate hydrogen gas (a potential fuel) by the endothermic reaction: C(s) + H2O(g) ⇌ CO(g) + H2(g) If this reaction mixture is at equilibrium, predict whether each disturbance will result in the formation of additional hydrogen gas, the formation of less hydrogen gas, or have no effect on the quantity of hydrogen gas. e. adding a catalyst to the reaction mixture

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Textbook Question

Carbon monoxide replaces oxygen in oxygenated hemoglobin according to the reaction: HbO2(aq) + CO(aq) ⇌ HbCO(aq) + O2(aq) a. Use the reactions and associated equilibrium constants at body temperature given here to find the equilibrium constant for the reaction just shown. Hb(aq) + O2(aq) ⇌ HbO2(aq) Kc = 1.8 Hb(aq) + CO(aq) ⇌ HbCO(aq) Kc = 306

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Textbook Question

At 650 K, the reaction MgCO3(s) ⇌ MgO(s) + CO2(g) has Kp = 0.026. A 10.0-L container at 650 K has 1.0 g of MgO(s) and CO2 at P = 0.0260 atm. The container is then compressed to a volume of 0.100 L. Find the mass of MgCO3 that is formed.

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Textbook Question

Consider the endothermic reaction: C2H4(g) + I2(g) ⇌ C2H4I2(g) If you were trying to maximize the amount of C2H4I2 produced, which tactic might you try? Assume that the reaction mixture reaches equilibrium. a. decreasing the reaction volume b. removing I2 from the reaction mixture c. raising the reaction temperature d. adding C2H4 to the reaction mixture

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Textbook Question

Consider the reaction: H2(g) + I2(g) ⇌ 2 HI(g) A reaction mixture at equilibrium at 175 K contains PH2 = 0.958 atm, PI2 = 0.877 atm, and PHI = 0.020 atm. A second reaction mixture, also at 175 K, contains PH2 = PI2 = 0.621 atm and PHI = 0.101 atm. Is the second reaction at equilibrium? If not, what will be the partial pressure of HI when the reaction reaches equilibrium at 175 K?

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Textbook Question

A reaction vessel at 27 °C contains a mixture of SO2 (P = 3.00 atm) and O2 (P = 1.00 atm). When a catalyst is added, this reaction takes place: 2 SO2( g) + O2( g) ⇌ 2 SO3( g). At equilibrium, the total pressure is 3.75 atm. Find the value of Kc.

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