Chapter 12, Problem 83b
The phase diagram for sulfur is shown here. The rhombic and monoclinic states are two solid states with different structures. b. Which of the two solid states of sulfur is more dense?
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Nitrogen has a normal boiling point of 77.3 K and a melting point (at 1 atm) of 63.1 K. Its critical temperature is 126.2 K and its critical pressure is 2.55 * 104 torr. It has a triple point at 63.1 K and 94.0 torr. Sketch the phase diagram for nitrogen. Does nitrogen have a stable liquid state at 1 atm?
Argon has a normal boiling point of 87.2 K and a melting point (at 1 atm) of 84.1 K. Its critical temperature is 150.8 K and its critical pressure is 48.3 atm. It has a triple point at 83.7 K and 0.68 atm. Sketch the phase diagram for argon. Which has the greater density, solid argon or liquid argon?
The phase diagram for sulfur is shown here. The rhombic and monoclinic states are two solid states with different structures. a. Below what pressure does solid sulfur sublime?
Water is a good solvent for many substances. What is the molecular basis for this property, and why is it significant?
Explain the observed trend in the melting points of the hydrogen halides.
HI -50.8 °C
HBr -88.5 °C
HCl -114.8 °C
HF -83.1 °C
Explain the observed trend in the boiling points of these compounds.
H2Te -2 °C
H2Se -41.5 °C
H2S -60.7 °C
H2O 100 °C