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Ch.12 - Liquids, Solids & Intermolecular Forces
Chapter 12, Problem 54

Explain why the viscosity of multigrade motor oils is less temperature-dependent than that of single-grade motor oils.

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1
Understand that viscosity is a measure of a fluid's resistance to flow, and it typically decreases as temperature increases.
Recognize that single-grade motor oils are designed to perform optimally at a specific temperature range, meaning their viscosity can change significantly outside this range.
Learn that multigrade motor oils contain special additives called viscosity index improvers, which help maintain a more consistent viscosity across a wider temperature range.
These viscosity index improvers are long-chain polymers that expand at higher temperatures, increasing the oil's resistance to thinning, and contract at lower temperatures, preventing the oil from becoming too thick.
Conclude that the presence of these additives in multigrade oils allows them to adapt better to temperature changes, making their viscosity less temperature-dependent compared to single-grade oils.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Viscosity

Viscosity is a measure of a fluid's resistance to flow. It indicates how thick or thin a liquid is, affecting how easily it moves. In general, higher viscosity means a thicker fluid that flows more slowly, while lower viscosity indicates a thinner fluid that flows more easily. Understanding viscosity is crucial for evaluating the performance of motor oils under different temperature conditions.
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Multigrade vs. Single-Grade Oils

Multigrade oils are formulated to perform well at a range of temperatures, typically indicated by two viscosity ratings (e.g., 10W-30). In contrast, single-grade oils have a fixed viscosity rating (e.g., 30W) and are designed for specific temperature ranges. The additives in multigrade oils help maintain a more stable viscosity across varying temperatures, making them less temperature-dependent than single-grade oils.
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Temperature Dependence of Viscosity

The viscosity of fluids generally decreases as temperature increases, meaning they flow more easily when heated. Single-grade oils experience significant changes in viscosity with temperature fluctuations, which can affect engine performance. Multigrade oils, however, are engineered with viscosity index improvers that minimize these changes, allowing them to maintain consistent performance across a broader temperature range.
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