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Ch.22 - Organic Chemistry
Chapter 22, Problem 53d

Name each alkyne. d.

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Identify the longest carbon chain that includes the triple bond. This will determine the base name of the alkyne.
Number the carbon chain starting from the end nearest to the triple bond to give the lowest possible number to the triple bond.
Identify and name any substituents attached to the main carbon chain.
Combine the names of the substituents with the base name of the alkyne, placing the substituents in alphabetical order and using numbers to indicate their positions on the chain.
Ensure the name follows IUPAC nomenclature rules, using the suffix '-yne' to indicate the presence of a triple bond.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Alkynes

Alkynes are a class of hydrocarbons characterized by at least one carbon-carbon triple bond (C≡C). They follow the general formula CnH2n-2, where 'n' is the number of carbon atoms. Alkynes are unsaturated compounds, meaning they contain fewer hydrogen atoms than alkanes and alkenes, which can affect their reactivity and properties.
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Nomenclature of Alkynes

The nomenclature of alkynes follows the IUPAC (International Union of Pure and Applied Chemistry) rules, which involve identifying the longest carbon chain containing the triple bond. The name is derived from the number of carbon atoms in the chain, with the suffix '-yne' indicating the presence of a triple bond. The position of the triple bond is indicated by a number, which corresponds to the first carbon of the triple bond in the chain.
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Isomerism in Alkynes

Alkynes can exhibit structural isomerism, where compounds have the same molecular formula but different structural arrangements. This can include variations in the position of the triple bond or the branching of the carbon chain. Understanding isomerism is crucial for naming and distinguishing between different alkynes, as each isomer can have distinct physical and chemical properties.
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