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Ch.14 - Solutions
Chapter 14, Problem 52a

An aqueous KNO3 solution is made using 72.5 g of KNO3 diluted to a total solution volume of 2.00 L. Calculate the molarity of the solution. (Assume a density of 1.05 g/mL for the solution.)

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insert step 1: Determine the molar mass of KNO3 by adding the atomic masses of potassium (K), nitrogen (N), and oxygen (O).
insert step 2: Convert the mass of KNO3 from grams to moles using the molar mass calculated in step 1.
insert step 3: Calculate the molarity of the solution by dividing the number of moles of KNO3 by the volume of the solution in liters.
insert step 4: Note that the density of the solution is provided, but it is not needed for calculating molarity as molarity is defined as moles per liter of solution.
insert step 5: Conclude with the molarity of the KNO3 solution, ensuring all units are consistent and correct.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molarity

Molarity is a measure of concentration defined as the number of moles of solute per liter of solution. It is expressed in units of moles per liter (mol/L). To calculate molarity, one must first determine the number of moles of the solute, which can be found using the formula: moles = mass (g) / molar mass (g/mol).
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Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). For KNO3, the molar mass can be calculated by summing the atomic masses of potassium (K), nitrogen (N), and three oxygen (O) atoms. This value is essential for converting grams of KNO3 into moles, which is necessary for calculating molarity.
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Solution Density

Density is defined as mass per unit volume and is crucial for converting between mass and volume in solutions. In this problem, the density of the KNO3 solution is given as 1.05 g/mL, which can be used to confirm the total mass of the solution if needed. However, for molarity calculations, the volume of the solution in liters is directly used, making density less critical in this specific context.
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