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Ch.8 - Periodic Properties of the Elements
Chapter 8, Problem 105

What are the general outer electron configurations (nsx npy) for groups 6A and 7A in the periodic table? The electron affinity of each group 7A element is more negative than that of each corresponding group 6A element. Use the electron configurations to explain why this is so.

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Identify the general outer electron configuration for group 6A elements, which is \( ns^2 np^4 \).
Identify the general outer electron configuration for group 7A elements, which is \( ns^2 np^5 \).
Understand that group 7A elements have one more electron in the p orbital compared to group 6A elements, making them one electron short of a full octet.
Recognize that group 7A elements have a strong tendency to gain an electron to achieve a stable noble gas configuration, resulting in a more negative electron affinity.
Explain that group 6A elements, while also tending to gain electrons, are less eager than group 7A elements because they need to gain two electrons to achieve a full octet, leading to a less negative electron affinity.
Related Practice
Open Question
Explain why vanadium (radius = 134 pm) and copper (radius = 128 pm) have nearly identical atomic radii, even though the atomic number of copper is about 25% higher than that of vanadium. Predict the relative densities of these two metals. Look up the densities in a reference book, periodic table, or on the Internet to check if your predictions are correct.
Open Question
The lightest noble gases, such as helium and neon, are completely inert—they do not form any chemical compounds whatsoever. In contrast, the heavier noble gases do form a limited number of compounds. Explain this difference in terms of trends in fundamental periodic properties.
Open Question
Why does the lightest halogen, which is also the most chemically reactive, exhibit a decrease in reactivity as you move down the column of halogens in the periodic table? Explain this trend in terms of periodic properties.
Open Question
Why is the electron affinity of each group 5A element more positive than that of each corresponding group 4A element? Use the outer electron configurations for these columns to suggest a reason for this observation.
Textbook Question

The elements with atomic numbers 35 and 53 have similar chemical properties. Based on their electronic configurations, predict the atomic number of a heavier element that also should share these chemical properties.

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Open Question
What are the electron configurations of the six cations that sulfur forms, by losing one to six electrons? For cations with unpaired electrons, please provide orbital diagrams.