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Ch.8 - Periodic Properties of the Elements
Chapter 8, Problem 107

The elements with atomic numbers 35 and 53 have similar chemical properties. Based on their electronic configurations, predict the atomic number of a heavier element that also should share these chemical properties.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Periodic Trends

Periodic trends refer to the patterns observed in the properties of elements as you move across or down the periodic table. Elements in the same group (column) often exhibit similar chemical properties due to their similar valence electron configurations. Understanding these trends helps predict the behavior of elements based on their position in the periodic table.
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Periodic Trends

Electronic Configuration

Electronic configuration describes the distribution of electrons in an atom's orbitals. It is crucial for determining an element's chemical properties, as the arrangement of electrons, particularly in the outermost shell, influences how an element interacts with others. For elements with atomic numbers 35 (Bromine) and 53 (Iodine), their configurations indicate they belong to the halogen group, which is characterized by similar reactivity.
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Electron Configuration Example

Halogens

Halogens are a group of elements in Group 17 of the periodic table, known for their high reactivity and tendency to form salts with metals. The halogens include fluorine, chlorine, bromine, iodine, and astatine. Elements in this group share similar chemical properties due to their similar electronic configurations, particularly having seven valence electrons, which drives their reactivity and bonding behavior.
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Halogenation Reactions
Related Practice
Open Question
Why does the lightest halogen, which is also the most chemically reactive, exhibit a decrease in reactivity as you move down the column of halogens in the periodic table? Explain this trend in terms of periodic properties.
Open Question
What are the general outer electron configurations (nsx npy) for groups 6A and 7A in the periodic table? The electron affinity of each group 7A element is more negative than that of each corresponding group 6A element. Use the electron configurations to explain why this is so.
Open Question
Why is the electron affinity of each group 5A element more positive than that of each corresponding group 4A element? Use the outer electron configurations for these columns to suggest a reason for this observation.
Open Question
What are the electron configurations of the six cations that sulfur forms, by losing one to six electrons? For cations with unpaired electrons, please provide orbital diagrams.
Textbook Question

You have cracked a secret code that uses elemental symbols to spell words. The code uses numbers to designate the elemental symbols. Each number is the sum of the atomic number and the highest principal quantum number of the highest occupied orbital of the element whose symbol is to be used. The message may be written forward or backward. Decode the following messages: a. 10, 12, 58, 11, 7, 44, 63, 66

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Textbook Question

Use Coulomb's law to calculate the ionization energy in kJ>mol of an atom composed of a proton and an electron separated by 100.00 pm. What wavelength of light has sufficient energy to ionize the atom?

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