Which is the larger species in each pair? a. Li or Li⁺ b. Cs^- or Cs⁺ c. Cr^- or Cr³⁺ d. O or O^2-

Key Concepts

Ionic Radius

Ionic radius refers to the size of an ion in a crystal lattice. Cations, which are positively charged ions, are generally smaller than their neutral atoms due to the loss of electrons, leading to reduced electron-electron repulsion. Conversely, anions, which are negatively charged ions, are larger than their neutral atoms because the addition of electrons increases repulsion among them, resulting in a larger size.

Charge and Size Relationship

The charge of an ion significantly affects its size. As the positive charge increases (e.g., from Cr to Cr³⁺), the ion becomes smaller due to the increased attraction between the nucleus and the remaining electrons. In contrast, when an atom gains electrons to form an anion, the size increases due to the added electron-electron repulsion, making the ion larger than its neutral counterpart.

Comparative Analysis of Ions

When comparing ions, it is essential to consider both their charge and the number of electrons. For example, when comparing Li and Li⁺, the neutral Li atom is larger than the Li⁺ ion. Similarly, when comparing Cs⁻ and Cs⁺, the Cs⁻ ion is larger due to the additional electron. This comparative analysis helps determine which species is larger in each pair presented in the question.