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Ch.8 - Periodic Properties of the Elements
Chapter 8, Problem 58

Arrange the atoms according to decreasing effective nuclear charge experienced by their valence electrons: S, Mg, Al, Si.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Effective Nuclear Charge (Z_eff)

Effective nuclear charge is the net positive charge experienced by an electron in a multi-electron atom. It accounts for the actual nuclear charge (number of protons) minus the shielding effect of inner-shell electrons. This concept is crucial for understanding how strongly valence electrons are attracted to the nucleus, influencing atomic size and reactivity.
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Shielding Effect

The shielding effect refers to the phenomenon where inner-shell electrons partially block the attraction between the nucleus and the valence electrons. This results in a lower effective nuclear charge felt by the outermost electrons. Understanding this effect is essential for predicting trends in atomic properties across the periodic table.
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Periodic Trends

Periodic trends are patterns observed in the properties of elements as you move across or down the periodic table. Key trends include atomic radius, ionization energy, and electronegativity, which are influenced by effective nuclear charge and shielding. Recognizing these trends helps in arranging elements based on their atomic characteristics, such as effective nuclear charge.
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Related Practice
Textbook Question

According to Coulomb's law, which pair of charged particles has the lowest potential energy? a. a particle with a 1- charge separated by 150 pm from a particle with a 2+ charge b. a particle with a 1- charge separated by 150 pm from a particle with a 1+ charge c. a particle with a 1- charge separated by 100 pm from a particle with a 3+ charge

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Textbook Question

According to Coulomb's law, rank the interactions between charged particles from lowest potential energy to highest potential energy. a. a 1+ charge and a 1- charge separated by 100 pm b. a 2+ charge and a 1- charge separated by 100 pm c. a 1+ charge and a 1+ charge separated by 100 pm d. a 1+ charge and a 1- charge separated by 200 pm

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Textbook Question

Which experience a greater effective nuclear charge: the valence electrons in beryllium or the valence electrons in nitrogen? Why?

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Textbook Question

If core electrons completely shielded valence electrons from nuclear charge (i.e., if each core electron reduced nuclear charge by 1 unit) and if valence electrons did not shield one another from nuclear charge at all, what would be the effective nuclear charge experienced by the valence electrons of each atom? a. K

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Textbook Question

If core electrons completely shielded valence electrons from nuclear charge (i.e., if each core electron reduced nuclear charge by 1 unit) and if valence electrons did not shield one another from nuclear charge at all, what would be the effective nuclear charge experienced by the valence electrons of each atom? b. Ca

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Textbook Question

In Section 3.6, we estimated the effective nuclear charge on beryllium's valence electrons to be slightly greater than 2+. What would a similar treatment predict for the effective nuclear charge on boron's valence electrons? Would you expect the effective nuclear charge to be different for boron's 2s electrons compared to its 2p electron? In what way? (Hint: Consider the shape of the 2p orbital compared to that of the 2s orbital.)

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