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Ch.6 - Thermochemistry
Chapter 6, Problem 93a

Determine the mass of CO2 produced by burning enough of each fuel to produce 1.00×102 kJ of heat. a. CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(g) ΔH°rxn = –802.3 kJ

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced chemical equation. It allows us to determine the amount of product formed or reactant consumed when a specific quantity of another substance is involved. In this case, it will help us calculate the mass of CO2 produced from the combustion of CH4 by using the given enthalpy change and the molar ratios from the reaction.
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Enthalpy Change (ΔH)

Enthalpy change (ΔH) is a measure of the heat energy absorbed or released during a chemical reaction at constant pressure. A negative ΔH indicates that the reaction is exothermic, meaning it releases heat. In this question, the ΔH of -802.3 kJ for the combustion of methane (CH4) indicates that burning one mole of CH4 releases this amount of energy, which is crucial for determining how much CO2 is produced for a specific heat output.
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Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is essential for converting between the mass of a substance and the number of moles. In this problem, knowing the molar mass of CO2 will allow us to convert the moles of CO2 produced from the stoichiometric calculations into grams, providing the final answer for the mass of CO2 generated from the combustion of methane.
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Related Practice
Textbook Question

Ethanol (C2H5OH) can be made from the fermentation of crops and has been used as a fuel additive to gasoline. Write a balanced equation for the combustion of ethanol and calculate ΔH°rxn.

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Textbook Question

Top fuel dragsters and funny cars burn nitromethane as fuel according to the balanced combustion equation: 2 CH3NO2(l) + 3/2O2(g) → 2 CO2(g) + 3 H2O(l) + N2(g) ΔH°rxn = –1418 kJ The enthalpy of combustion for nitromethane is –709.2 kJ/mol. Calculate the standard enthalpy of formation (ΔH°f ) for nitromethane.

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Textbook Question

The explosive nitroglycerin (C3H5N3O9) decomposes rapidly upon ignition or sudden impact according to the balanced equation: 4 C3H5N3O9(l) → 12 CO2(g) + 10 H2O(g) + 6 N2(g) + O2(g) ΔH°rxn = –5678 kJ Calculate the standard enthalpy of formation (ΔH°f ) for nitroglycerin.

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Textbook Question

Methanol (CH3OH) has been suggested as a fuel to replace gasoline. Find ΔH°rxn, and determine the mass of carbon dioxide emitted per kJ of heat produced. Use the information from the previous exercise to calculate the same quantity for octane, C8H18. How does methanol compare to octane with respect to global warming?

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Open Question
The citizens of the world burn the fossil fuel equivalent of 7 * 10^12 kg of petroleum per year. Assume that all of this petroleum is in the form of octane (C8H18) and calculate how much CO2 (in kg) the world produces from fossil fuel combustion per year. (Hint: Begin by writing a balanced equation for the combustion of octane.) If the atmosphere currently contains approximately 3 * 10^15 kg of CO2, how long will it take for the world’s fossil fuel combustion to double the amount of atmospheric carbon dioxide?
Textbook Question

In a sunny location, sunlight has a power density of about 1 kW/m2. Photovoltaic solar cells can convert this power into electricity with 15% efficiency. If a typical home uses 385 kWh of electricity per month, how many square meters of solar cells are required to meet its energy requirements? Assume that electricity can be generated from the sunlight for 8 hours per day.

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