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Ch.6 - Thermochemistry
Chapter 6, Problem 68

A 2.85-g lead weight, initially at 10.3 °C, is submerged in 7.55 g of water at 52.3 °C in an insulated container. What is the final temperature of both substances at thermal equilibrium?

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Identify the concept of thermal equilibrium, where the heat lost by the hotter substance (water) equals the heat gained by the cooler substance (lead).
Use the formula for heat transfer: \( q = mc\Delta T \), where \( q \) is the heat absorbed or released, \( m \) is the mass, \( c \) is the specific heat capacity, and \( \Delta T \) is the change in temperature.
Set up the equation for thermal equilibrium: \( m_{\text{lead}}c_{\text{lead}}(T_f - T_{\text{initial, lead}}) = -m_{\text{water}}c_{\text{water}}(T_f - T_{\text{initial, water}}) \).
Substitute the known values: \( m_{\text{lead}} = 2.85 \text{ g} \), \( c_{\text{lead}} = 0.128 \text{ J/g°C} \), \( T_{\text{initial, lead}} = 10.3 \text{ °C} \), \( m_{\text{water}} = 7.55 \text{ g} \), \( c_{\text{water}} = 4.18 \text{ J/g°C} \), \( T_{\text{initial, water}} = 52.3 \text{ °C} \).
Solve the equation for \( T_f \), the final temperature, which will be the same for both substances at thermal equilibrium.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Thermal Equilibrium

Thermal equilibrium occurs when two substances at different temperatures come into contact and exchange heat until they reach the same temperature. In this scenario, the lead weight and water will transfer heat between each other until they stabilize at a common final temperature, which can be calculated using the principle of conservation of energy.
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Specific Heat Capacity

Specific heat capacity is the amount of heat required to raise the temperature of a unit mass of a substance by one degree Celsius. Each material has a unique specific heat capacity, which influences how much its temperature changes when heat is added or removed. In this problem, the specific heat capacities of lead and water will be essential for calculating the final temperature.
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Heat Transfer Calculation

Heat transfer calculations involve determining the amount of heat lost or gained by a substance during a temperature change. This is typically expressed using the formula Q = mcΔT, where Q is the heat transferred, m is the mass, c is the specific heat capacity, and ΔT is the change in temperature. In this case, the heat lost by the water will equal the heat gained by the lead weight, allowing for the calculation of the final equilibrium temperature.
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Related Practice
Textbook Question

A silver block, initially at 58.5 °C, is submerged into 100.0 g of water at 24.8 °C, in an insulated container. The final temperature of the mixture upon reaching thermal equilibrium is 26.2 °C. What is the mass of the silver block?

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Textbook Question

A 32.5-g iron rod, initially at 22.7 °C, is submerged into an unknown mass of water at 63.2 °C, in an insulated container. The final temperature of the mixture upon reaching thermal equilibrium is 59.5 °C. What is the mass of the water?

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Textbook Question

A 31.1-g wafer of pure gold, initially at 69.3 °C, is submerged into 64.2 g of water at 27.8 °C in an insulated container. What is the final temperature of both substances at thermal equilibrium?

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Textbook Question

Two substances, A and B, initially at different temperatures, come into contact and reach thermal equilibrium. The mass of substance A is 6.15 g and its initial temperature is 20.5 °C. The mass of substance B is 25.2 g and its initial temperature is 52.7 °C. The final temperature of both substances at thermal equilibrium is 46.7 °C. If the specific heat capacity of substance B is 1.17 J/g•°C, what is the specific heat capacity of substance A?

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Textbook Question

Exactly 1.5 g of a fuel burns under conditions of constant pressure and then again under conditions of constant volume. In measurement A the reaction produces 25.9 kJ of heat, and in measurement B the reaction produces 23.3 kJ of heat. Which measurement (A or B) corresponds to conditions of constant pressure? Explain.

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Open Question
Should you carry out a chemical reaction under conditions of constant volume or constant pressure to obtain the largest possible amount of heat, if there is a large increase in the number of moles of gas? Explain.