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Ch.21 - Organic Chemistry
Chapter 21, Problem 68b

Draw the structure for each compound. b. 1-iodo-2-methylbenzene

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Identify the base structure: The base structure is benzene, which is a six-carbon ring with alternating double bonds, represented as a hexagon with a circle inside or alternating double lines.
Locate the substituents: The compound name '1-iodo-2-methylbenzene' indicates two substituents on the benzene ring: an iodine (I) atom and a methyl (CH₃) group.
Assign positions: The '1-' and '2-' in the name indicate the positions of the substituents on the benzene ring. Position 1 is typically where you start numbering, and position 2 is the next carbon in the ring.
Draw the iodine substituent: Place the iodine atom (I) on carbon 1 of the benzene ring.
Draw the methyl substituent: Place the methyl group (CH₃) on carbon 2 of the benzene ring, adjacent to the iodine atom.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Benzene Structure

Benzene is a cyclic hydrocarbon with a formula of C6H6, characterized by a ring of six carbon atoms with alternating double bonds, often represented as a hexagon with a circle inside. This structure exhibits resonance, meaning the electrons are delocalized, contributing to its stability and unique chemical properties. Understanding the basic structure of benzene is essential for drawing derivatives like 1-iodo-2-methylbenzene.
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Substitution Reactions

In organic chemistry, substitution reactions involve replacing one atom or group in a molecule with another. In the case of aromatic compounds like benzene, electrophilic aromatic substitution is common, where an electrophile replaces a hydrogen atom. Recognizing how substituents like iodine and methyl affect the benzene ring is crucial for accurately drawing the structure of 1-iodo-2-methylbenzene.
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Nomenclature of Organic Compounds

The IUPAC nomenclature system provides a standardized method for naming organic compounds based on their structure. For 1-iodo-2-methylbenzene, the name indicates that an iodine atom is attached to the first carbon and a methyl group to the second carbon of the benzene ring. Familiarity with this naming convention is vital for interpreting and constructing chemical structures correctly.
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