Chapter 19, Problem 44a
Sketch a voltaic cell for each redox reaction. Label the anode and cathode and indicate the half-reaction that occurs at each electrode and the species present in each solution. Also indicate the direction of electron flow. a. Ni2+(aq) + Mg(s) ¡ Ni(s) + Mg2+(aq)
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Balance each redox reaction occurring in basic aqueous solution. a. MnO4-(aq) + Br-(aq) ¡ MnO2(s) + BrO3-(aq)
Balance each redox reaction occurring in basic aqueous solution. b. Ag(s) + CN-(aq) + O2(g) ¡ Ag(CN)2-(aq)
Balance each redox reaction occurring in basic aqueous solution. c. NO2-(aq) + Al(s) ¡ NH3(g) + AlO2-(aq)
Calculate the standard cell potential for each of the electro- chemical cells in Problem 43.
Consider the voltaic cell:
d. Indicate the direction of anion and cation flow in the salt bridge
Use line notation to represent each electrochemical cell in Problem 43.