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Ch.19 - Electrochemistry
Chapter 19, Problem 124

A metal forms the fluoride MF3. Electrolysis of the molten fluo- ride by a current of 3.86 A for 16.2 minutes deposits 1.25 g of the metal. Calculate the molar mass of the metal.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electrolysis

Electrolysis is a chemical process that uses electrical energy to drive a non-spontaneous reaction. In this context, it involves passing an electric current through molten fluoride to decompose it into its constituent elements, allowing for the deposition of the metal. The amount of substance deposited can be calculated using Faraday's laws of electrolysis, which relate the quantity of electric charge to the amount of substance transformed.
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Faraday's Laws of Electrolysis

Faraday's laws state that the amount of substance deposited during electrolysis is directly proportional to the electric charge passed through the electrolyte. The first law quantifies this relationship, while the second law relates the amount of substance to its equivalent weight. These laws are essential for calculating the molar mass of the metal in the given problem, as they allow us to connect the current, time, and mass of the deposited metal.
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Molar Mass Calculation

Molar mass is defined as the mass of one mole of a substance, typically expressed in grams per mole (g/mol). To calculate the molar mass of the metal in this scenario, we first determine the number of moles of metal deposited using the mass and then apply the relationship between moles, charge, and the number of electrons transferred during electrolysis. This calculation is crucial for identifying the identity of the metal based on its molar mass.
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