Chapter 19, Problem 124
A metal forms the fluoride MF3. Electrolysis of the molten fluo- ride by a current of 3.86 A for 16.2 minutes deposits 1.25 g of the metal. Calculate the molar mass of the metal.
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Calculate ∆Gr°xn and K for each reaction.
a. The disproportionation of Mn2+(aq) to Mn(s) and MnO2(s) in acid solution at 25 °C.
Calculate ∆Gr°xn and K for each reaction. a. The reaction of Cr2+(aq) with Cr2O7^2-(aq) in acid solution to form Cr3+(aq).
Calculate ∆Gr°xn and K for each reaction. b. The reaction of Cr3+(aq) and Cr(s) to form Cr2+(aq). [The electrode potential of Cr2+(aq) to Cr(s) is -0.91 V.]
A sample of impure tin of mass 0.535 g is dissolved in strong acid to give a solution of Sn2+. The solution is then titrated with a 0.0448 M solution of NO3-, which is reduced to NO(g). The equivalence point is reached upon the addition of 0.0344 L of the NO3- solution. Find the percent by mass of tin in the original sample, assuming that it contains no other reducing agents.
A current of 11.3 A is applied to 1.25 L of a solution of 0.552 M HBr converting some of the H+ to H2(g), which bubles out of solution. What is the pH of the solution after 73 minutes?
An MnO2(s)/Mn2+(aq) electrode in which the pH si 10.24 is prepared. Find the [Mn2+] necessary to lower the potential of the half-cell to 0.00 V (at 25°C)