Skip to main content
Ch.16 - Acids and Bases
Chapter 16, Problem 91

Caffeine (C8H10N4O2) is a weak base with a pKb of 10.4. Calculate the pH of a solution containing a caffeine concentration of 455 mg/L.

Verified Solution

Video duration:
4m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Weak Bases and pKb

A weak base is a substance that partially ionizes in solution, establishing an equilibrium between the base and its conjugate acid. The pKb value indicates the strength of the base; a higher pKb means a weaker base. In this case, caffeine has a pKb of 10.4, which suggests it does not ionize significantly in water, affecting the pH calculation.
Recommended video:
Guided course
00:51
ICE Charts of Weak Bases

pH and pOH Relationship

pH is a measure of the hydrogen ion concentration in a solution, while pOH measures the hydroxide ion concentration. The relationship between pH and pOH is given by the equation pH + pOH = 14 at 25°C. Understanding this relationship is crucial for calculating the pH of a solution when dealing with weak bases, as it allows for the determination of hydroxide ion concentration from the base's ionization.
Recommended video:
Guided course
02:09
pH and pOH Calculations

Concentration and Molarity

Concentration refers to the amount of solute present in a given volume of solution, often expressed in molarity (moles per liter). To calculate the pH of the caffeine solution, it is necessary to convert the given mass (455 mg) into moles and then into molarity. This conversion is essential for applying the equilibrium expression related to the weak base and determining the resulting pH.
Recommended video:
Guided course
00:53
Molarity Concept