Write net ionic equations for the reactions that take place when aqueous solutions of the following substances are mixed: a. sodium cyanide and nitric acid b. ammonium chloride and sodium hydroxide c. sodium cyanide and ammonium bromide d. potassium hydrogen sulfate and lithium acetate e. sodium hypochlorite and ammonia
Ch.16 - Acids and Bases
Chapter 16, Problem 144
What is the concentration of ammonia in a solution prepared by dissolving 0.10 mol of acetic acid and 0.10 mol of ammonium chloride in enough water to make 1.0 L of solution?
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1
Identify the relevant chemical reaction: Ammonium chloride (NH4Cl) dissociates in water to form ammonium ions (NH4+) and chloride ions (Cl-).
Recognize that ammonium ions (NH4+) can react with water to form ammonia (NH3) and hydronium ions (H3O+). This is an example of an acid-base equilibrium.
Write the equilibrium expression for the reaction: NH4+ + H2O ⇌ NH3 + H3O+. The equilibrium constant expression (Ka) for this reaction is Ka = [NH3][H3O+]/[NH4+].
Use the initial concentrations: Initially, [NH4+] = 0.10 M and [NH3] = 0 M. Assume x is the change in concentration at equilibrium, so [NH3] = x and [NH4+] = 0.10 - x.
Substitute the equilibrium concentrations into the Ka expression and solve for x, which represents the concentration of ammonia (NH3) at equilibrium.
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Morphine has the formula C17H19NO3. It is a base and accepts one proton per molecule. It is isolated from opium. A 0.682-g sample of opium is found to require 8.92 mL of a 0.0116 M solution of sulfuric acid for neutralization. Assuming that morphine is the only acid or base present in opium, calculate the percent morphine in the sample of opium.
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The pH of a 1.00 M solution of urea, a weak organic base, is 7.050. Calculate the Ka of protonated urea.
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Lactic acid is a weak acid found in milk. Its calcium salt is a source of calcium for growing animals. A saturated solution of this salt, which we can represent as Ca(Lact)2, has a [Ca2+] = 0.26 M and a pH = 8.78. Assuming the salt is completely dissociated, calculate the Ka of lactic acid.
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Open Question
A solution of 0.23 mol of the chloride salt of protonated quinine (QH+), a weak organic base, in 1.0 L of solution has a pH of 4.58. What is the Kb of quinine (Q)?