Argon has a normal boiling point of 87.2 K and a melting point (at 1 atm) of 84.1 K. Its critical temperature is 150.8 K and its critical pressure is 48.3 atm. It has a triple point at 83.7 K and 0.68 atm. Sketch the phase diagram for argon. Which has the greater density, solid argon or liquid argon?
Ch.11 - Liquids, Solids & Intermolecular Forces
Chapter 11, Problem 79
Water has a high boiling point given its relatively low molar mass. Why?
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1
Identify the key property of water that contributes to its high boiling point: hydrogen bonding.
Explain that water molecules are polar, with a partial negative charge on the oxygen atom and a partial positive charge on the hydrogen atoms.
Describe how the polarity of water molecules leads to hydrogen bonding, where the hydrogen atom of one water molecule is attracted to the oxygen atom of another water molecule.
Discuss how hydrogen bonds are relatively strong intermolecular forces compared to other types of van der Waals forces, such as London dispersion forces or dipole-dipole interactions.
Conclude that the presence of these strong hydrogen bonds requires more energy (in the form of heat) to break, resulting in a higher boiling point for water compared to other molecules of similar molar mass.
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The phase diagram for sulfur is shown here. The rhombic and monoclinic states are two solid states with different structures. b. Which of the two solid states of sulfur is more dense?
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Water is a good solvent for many substances. What is the molecular basis for this property, and why is it significant?
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Explain the role of water in moderating Earth's climate.
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How is the density of solid water compared to that of liquid water atypical among substances, and why is this significant?