Using the molecular orbital energy ordering for second-row homonuclear diatomic molecules in which the π2p orbitals lie at lower energy than the σ2p, draw MO energy diagrams and predict the bond order in a molecule or ion with each number of total valence electrons. Will the molecule or ion be diamagnetic or paramagnetic? a. 4 b. 6
Ch.10 - Chemical Bonding II: Molecular Shapes & Valence Bond Theory
All textbooksTro 4th EditionCh.10 - Chemical Bonding II: Molecular Shapes & Valence Bond TheoryProblem 31
Chapter 10, Problem 31
A molecule with the formula AB3 has a trigonal pyramidal geometry. How many electron groups are on the central atom (A)?
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Molecular Geometry
Molecular geometry refers to the three-dimensional arrangement of atoms within a molecule. It is determined by the number of bonding pairs and lone pairs of electrons around the central atom. In the case of AB3 with trigonal pyramidal geometry, the arrangement is influenced by the presence of lone pairs that repel bonding pairs, leading to a specific shape.
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Electron Groups
Electron groups include both bonding pairs of electrons (shared between atoms) and lone pairs (non-bonding electrons) around a central atom. The total number of electron groups determines the molecular geometry according to the VSEPR (Valence Shell Electron Pair Repulsion) theory. For a trigonal pyramidal shape, the central atom must have four electron groups.
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VSEPR Theory
VSEPR (Valence Shell Electron Pair Repulsion) theory is a model used to predict the geometry of molecules based on the repulsion between electron pairs. According to this theory, electron groups will arrange themselves as far apart as possible to minimize repulsion. In the case of AB3, the presence of one lone pair leads to a trigonal pyramidal shape, indicating that there are four electron groups around the central atom.
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Related Practice
Textbook Question
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Open Question
What is the molecular geometry of BrF5, and how can it be sketched using the bond conventions shown in 'Representing Molecular Geometries on Paper' in Section 10.4?
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Sketch the antibonding molecular orbital that results from the linear combination of two 1s orbitals. Indicate the region where interference occurs and state the type of interference (constructive or destructive).
Textbook Question
A molecule with the formula AB3 has a trigonal planar geometry. How many electron groups are on the central atom?
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Textbook Question
For each molecular geometry, list the number of total electron groups, the number of bonding groups, and the number of lone pairs on the central atom. (c)
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Textbook Question
Determine the electron geometry, molecular geometry, and idealized bond angles for each molecule. In which cases do you expect deviations from the idealized bond angle? a. PF3 b. SBr2 c. CHCl3 d. CS2
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