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Ch.9 - Thermochemistry: Chemical Energy
Chapter 9, Problem 89

A 110.0 g piece of molybdenum metal is heated to 100.0 °C and placed in a calorimeter that contains 150.0 g of water at 24.6 °C. The system reaches equilibirum at a final temeprature of 28.0 °C. Calcualte the specific heat of molybdenum metal in J/g·°C. The specific heat of water is 4.18 J/g·°C

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Specific Heat Capacity

Specific heat capacity is the amount of heat required to raise the temperature of one gram of a substance by one degree Celsius. It is a crucial property that varies between different materials, influencing how they absorb and transfer heat. In this problem, the specific heat of water is given, and the specific heat of molybdenum needs to be calculated based on the heat exchange between the two substances.
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Heat Transfer and Equilibrium

Heat transfer occurs when thermal energy moves from a hotter object to a cooler one until thermal equilibrium is reached, meaning both objects attain the same temperature. In this scenario, the heat lost by the molybdenum as it cools down is equal to the heat gained by the water as it warms up. This principle is essential for setting up the equation to solve for the specific heat of molybdenum.
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Calorimetry

Calorimetry is the science of measuring the heat of chemical reactions or physical changes. In this context, a calorimeter is used to measure the heat exchange between the molybdenum and water. By applying the formula Q = mcΔT, where Q is heat, m is mass, c is specific heat, and ΔT is the change in temperature, we can calculate the specific heat of molybdenum based on the data provided.
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Related Practice
Textbook Question
Instant hot packs contain a solid and a pouch of water. When the pack is squeezed, the pouch breaks and the solid dis- solves, increasing the temperature because of the exothermic reaciton. The following reaction is used to make a hot pack: H2O LiCl1s2 ¡ Li 1aq2 + Cl 1aq2 ∆H = -36.9 kJ. What is the final temperature in a squeezed hot pack that contains 25.0 g of LiCl dissolved# in 125 mL of water? Assume a specific heat of 4.18 J>1g °C2 for the solution, an initial temperature of 25.0 °C, and no heat transfer between the hot pack and the environment.
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Textbook Question
When 0.187 g of benzene, C6H6, is burned in a bomb calorimeter the temperature rises by 3.45 °C. If the heat capacity of the calorimeter is 2.46 kJ>°C, calculate the combustion energy 1∆E2 for benzene in units of kJ/g and kJ/mol.
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Textbook Question
When 1.50 g of magnesium metal is allowed to react with 200 mL of 6.00 M aqueous HCl, the temperature rises from 25.0 °C to 42.9 °C. Calculate ΔH in kilojoules for the reaction, assumign that the heat capacity of the calorimeter is 776 J/°C, that the specific heat of the final soltuion is the same as that of water [4.18 J(g·°C)] and that the density of the solution is 1.00 g/mL
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Textbook Question
Citric acid has three dissociable hydrogens. When 5.00 mL of 0.64 M citric acid and 45.00 mL of 0.77 M NaOH are mixed at an initial temperature of 26.0 °C, the temperature rises to 27.9 °C as the citric acid is neutralized. The combined mixture ahs a mass of 51.6 g and a specific heat of 4.0 J/(g·°C). Assuming that no heat is transferred to the surroundings, cal- culate the enthalpy change for the reaction of 1.00 mol of cit- ric acid in kJ. Is the reaction exothermic or endothermic?
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Textbook Question
What is Hess's law, and why does it 'work'?
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Textbook Question
The following steps occur in the reaction of ethyl alcohol (CH3CH2OH) wiht oxygen to yield acetic acid (CH3CO2H). Show that equations 1 and 2 sum to give the net equation and calculate ΔH° for the net equation. (1) CH3CH2OH(l) + 1/2 O2(g) → CH3CHO (g) + H2O(l) ΔH° = -174.2 kJ (2) CH3CHO(g) + 1/2 O2(g) → CH3CO2H(l) ΔH° = -318.4 kJ (Net) CH3CH2OH(l) + O2(g) → CH3CO2H(l) + H2O(l) ΔH° = ?
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