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Ch.8 - Covalent Compounds: Bonding Theories and Molecular Structure
Chapter 8, Problem 75

The odor of cinnamon oil is due to cinnamaldehyde, C9H8O. What is the hybridization of each carbon atom in cinnamaldehyde? How many s and how many p bonds does cinnamaldehyde have? Chemical structure of cinnamaldehyde, showing carbon and hydrogen atoms.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Hybridization

Hybridization is the concept that describes the mixing of atomic orbitals to form new hybrid orbitals, which can explain the geometry of molecular bonding. In organic molecules like cinnamaldehyde, carbon atoms can exhibit different hybridizations (sp, sp2, sp3) depending on their bonding environment. For example, sp2 hybridization occurs in carbon atoms involved in double bonds, leading to a trigonal planar arrangement.
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Types of Bonds

In chemistry, bonds between atoms can be classified as sigma (σ) and pi (π) bonds. Sigma bonds are formed by the head-on overlap of orbitals and are present in all single bonds, while pi bonds result from the side-to-side overlap of p orbitals and are found in double and triple bonds. Understanding the number of each type of bond in a molecule is crucial for determining its structure and reactivity.
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Bonding Types

Molecular Structure

The molecular structure of a compound refers to the arrangement of its atoms and the types of bonds connecting them. In cinnamaldehyde, the structure includes a carbonyl group (C=O) and a double bond between carbon atoms, which influences its physical properties and reactivity. Analyzing the structure helps in identifying hybridization and the total number of bonds present in the molecule.
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