Ch.8 - Covalent Compounds: Bonding Theories and Molecular Structure
All textbooksMcMurry 8th EditionCh.8 - Covalent Compounds: Bonding Theories and Molecular StructureProblem 7
Chapter 8, Problem 7
The connections between atoms in the amino acid histidine are shown. Complete the electron-dot structure by adding multiple bonds and lone pairs of electrons. Give the hybridization on the numbered carbon and nitrogen atoms. (LO 8.4)
(a) N1 = sp2, N2 = sp, C1 = sp2, C2 = sp3 (b) N1 = sp2, N2 = sp2, C1 = sp3, C2 = sp2 (c) N1 = sp3, N2 = sp, C1 = sp2, C2 = sp3 (d) N1 = sp3, N2 = sp2, C1 = sp2, C2 = sp3Verified Solution
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Related Practice
Textbook Question
Give the geometry and approximate bond angles around the
central atom in CCl3-. (LO 8.1)
(a) Trigonal planar, 120°
(b) Trigonal pyramidal, 109.5°
(c) Trigonal pyramidal, 120°
(d) Bent, 109.5°
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Textbook Question
The following diagrams illustrate p-p orbital overlap or s-p
orbital overlap. Which diagram represents a p bond in valence
bond theory? (LO 8.3)
(a)
(b)
(c)
(d)
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Textbook Question
Which of the following molecules has a central atom with
sp3 hybridization? (LO 8.4)
(a) PCl5 (b) OF2
(c) CO2 (d) SF4
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Textbook Question
Use the chemical structure for Tagamet, a drug used to treat
peptic ulcers and heartburn, to answer questions 8 and 9.
Which orbitals overlap to form bond 1? (LO 8.5)
(a) s bond: N 1sp22 with C 1sp22; p bond: N (p) with C (p)
(b) N 1sp22 with C 1sp22
(c) s bond: N 1sp22 with C 1sp22; p bond: N 1sp22 with
C 1sp22
(d) s bond: N (sp) with C 1sp22; p bond: N (p) with C (p)
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Textbook Question
Use the chemical structure for Tagamet, a drug used to treat
peptic ulcers and heartburn, to answer questions 8 and 9.
Which orbitals overlap to form bond 2? (LO 8.5)
(a) C (sp) with C (sp) (b) C (sp) with C 1sp22
(c) C 1sp22 with C 1sp22 (d) C 1sp32 with C 1sp22
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Textbook Question
The C2 molecule has a MO diagram similar to N2
(Figure 8.22a). What is the bond order of C2 and is it paramagnetic
or diamagnetic? (LO 8.12)
(a) Bond order = 2, diamagnetic
(b) Bond order = 2, paramagnetic
(c) Bond order = 0, paramagnetic
(d) Bond order = 3>2, diamagnetic
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