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Ch.7 - Covalent Bonding and Electron-Dot Structures
Chapter 7, Problem 76

Which compound do you expect to have the stronger N-N bond, N2H2 or N2H4? Explain.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Bond Order

Bond order refers to the number of chemical bonds between a pair of atoms. In general, a higher bond order indicates a stronger bond. For nitrogen compounds, the bond order can be influenced by the presence of lone pairs and the overall molecular structure, affecting the strength of the N-N bond in N2H2 and N2H4.
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Hybridization

Hybridization is the concept of mixing atomic orbitals to form new hybrid orbitals that can accommodate bonding. In nitrogen compounds, the hybridization state can affect bond angles and bond strengths. For example, N2H2 has sp2 hybridization, while N2H4 has sp3 hybridization, which can influence the N-N bond strength.
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Steric Hindrance

Steric hindrance refers to the repulsion between atoms due to their physical size and spatial arrangement. In N2H4, the presence of additional hydrogen atoms creates more steric hindrance compared to N2H2, potentially weakening the N-N bond. Understanding steric effects is crucial for predicting bond strength in molecular structures.