Chapter 6, Problem 15
Which element has the largest atomic radius? (LO 5.20) (a) Rb (b) Co (c) Mg d) As
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Which molecular scale image best represents the ionic com-pound that forms between cesium and chlorine? (Cesium is represented by red circles, and chlorine is represented by blue circles.) (LO 6.12) (a)
(b)
(c)
(d)
Given the following information, construct a Born–Haber cycle to calculate the lattice energy of CaCl2(s). (LO 6.13)
Net energy change for the formation of CaCl2(s) form Ca(s) and Cl2(g) = -795.4 kJ/mol
Heat of sublimation for Ca(s) = +178 kJ/mol
Ei1 for Ca(s) = +590 kJ/mol
Ei2 for Ca(g) = +1145 kJ/mol
Bond dissociation energy for Cl2(g) = +243 kJ/mol
Eea1 for Cl(g) = -348.6 kJ/mol
(a) 2603 kJ/mol (b) 2254 kJ/mol (c) 2481 kJ/mo (d) 1663 kJ/mol
Three binary compounds are represented on the following drawing: red with red, blue with blue, and green with green. Give a likely formula for each compound.
Given the following values for steps in the formation of CaO(s) from its elements, draw a Born–Haber cycle similar to that shown in Figure 6.7. Eea1 for O1g2 = -141 kJ/mol Eea2 for O1g2 = 745.1 kJ/mol Heat of sublimation for Ca1s2 = 178 kJ/mol Ei1 for Ca1g2 = 590 kJ/mol Ei1 for Ca1g2 = 1145 kJ/mol Bond dissociation energy for O21g2 = 498 kJ/mol Lattice energy for CaO1s2 = 3401 kJ/mol