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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 76

Which of the following substances are likely to be soluble in water? (a) PbSO4 (b) Ba(NO3)2 (c) SnCO3 (d) (NH4)3PO4

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Solubility Rules

Solubility rules are guidelines that help predict whether a compound will dissolve in water. For example, most nitrates and ammonium salts are soluble, while many sulfates and carbonates have exceptions. Understanding these rules is essential for determining the solubility of various ionic compounds in aqueous solutions.
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Ionic Compounds

Ionic compounds are formed from the electrostatic attraction between positively and negatively charged ions. Their solubility in water depends on the strength of these ionic bonds compared to the interactions with water molecules. Compounds with weaker ionic bonds or those that can form favorable interactions with water are more likely to be soluble.
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Hydration Energy

Hydration energy refers to the energy released when ions are surrounded by water molecules. This energy can help overcome the lattice energy of ionic compounds, allowing them to dissolve. A higher hydration energy typically indicates greater solubility, as it compensates for the energy required to break the ionic bonds in the solid state.
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