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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 128

What is the molar concentration of As(III) in a solution if 22.35 mL of 0.100 M KBrO3 is needed for complete reaction with 50.00 mL of the As(III) solution? The balanced equation is:

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molarity

Molarity is a measure of concentration defined as the number of moles of solute per liter of solution. It is expressed in moles per liter (M). Understanding molarity is essential for calculating the concentration of a substance in a solution, especially when dealing with reactions where volumes and concentrations of reactants are involved.
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Stoichiometry

Stoichiometry is the branch of chemistry that deals with the relationships between the quantities of reactants and products in a chemical reaction. It involves using balanced chemical equations to determine how much of each substance is consumed or produced. In this question, stoichiometry is crucial for relating the volume and concentration of KBrO3 to the concentration of As(III) in the solution.
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Balanced Chemical Equation

A balanced chemical equation represents a chemical reaction with equal numbers of each type of atom on both sides of the equation. It provides the mole ratios needed to relate the amounts of reactants and products. In this case, the balanced equation will allow us to determine how the moles of KBrO3 used relate to the moles of As(III) present in the solution, which is necessary for calculating its molar concentration.
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Related Practice
Textbook Question
How many milliliters of 0.250 M Na2S2O3 solution is needed for complete reaction with 2.486 g of I2 according to the equation in Problem 4.124?
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Textbook Question
Dichromate ion, Cr2O7 2-, reacts with aqueous iron(II) ion in acidic solution according to the balanced equation What is the concentration of Fe2+ if 46.99 mL of 0.2004 M K2Cr2O7 is needed to titrate 50.00 mL of the Fe2+ solution?
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Textbook Question
A volume of 18.72 mL of 0.1500 M K2Cr2O7 solution was required to titrate a sample of FeSO4 according to the equation in Problem 4.126. What is the mass of the sample?
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Textbook Question
Standardized solutions of KBrO3 are frequently used in redox titrations. The necessary solution can be made by dissolving KBrO3 in water and then titrating it with an As(III) solution. What is the molar concentration of a KBrO3 solution if 28.55 mL of the solution is needed to titrate 1.550 g of As2O3? See Problem 4.128 for the balanced equation. (As2O3 dissolves in aqueous acid solution to yield H3AsO3: As2O3 + 3 H2OS 2 H3AsO3.)
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Textbook Question
The metal content of iron in ores can be determined by a redox procedure in which the sample is first oxidized with Br2 to convert all the iron to Fe3+ and then titrated with Sn2+ to reduce the Fe3+ to Fe2+. The balanced equation is: What is the mass percent Fe in a 0.1875 g sample of ore if 13.28 mL of a 0.1015 M Sn2+ solution is needed to titrate the Fe3+?
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Textbook Question
The concentration of the Sn2+ solution used in Problem 4.130 can be found by letting it react with a known amount of Fe2+. What is the molar concentration of an Sn2+ solution if 23.84 mL is required for complete reaction with 1.4855 g of Fe2O3?
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