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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 130

The metal content of iron in ores can be determined by a redox procedure in which the sample is first oxidized with Br2 to convert all the iron to Fe3+ and then titrated with Sn2+ to reduce the Fe3+ to Fe2+. The balanced equation is: What is the mass percent Fe in a 0.1875 g sample of ore if 13.28 mL of a 0.1015 M Sn2+ solution is needed to titrate the Fe3+?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Redox Reactions

Redox reactions involve the transfer of electrons between two species, resulting in oxidation and reduction processes. In this context, Br2 oxidizes Fe to Fe3+, while Sn2+ reduces Fe3+ back to Fe2+. Understanding these electron transfer processes is crucial for analyzing the stoichiometry of the reaction and calculating the amount of iron present in the sample.
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Titration

Titration is a quantitative analytical technique used to determine the concentration of a solute in a solution. In this case, the titration of Fe3+ with Sn2+ allows for the calculation of the amount of iron in the ore sample. The volume and molarity of the titrant (Sn2+) used in the reaction are essential for determining the moles of Fe3+ and, subsequently, the mass percent of iron in the sample.
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Mass Percent Calculation

Mass percent is a way to express the concentration of a component in a mixture, calculated as the mass of the component divided by the total mass of the mixture, multiplied by 100. To find the mass percent of Fe in the ore sample, one must first determine the mass of Fe from the titration data and then relate it to the original mass of the ore sample. This concept is fundamental for expressing the results of the analysis in a meaningful way.
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Related Practice
Textbook Question
A volume of 18.72 mL of 0.1500 M K2Cr2O7 solution was required to titrate a sample of FeSO4 according to the equation in Problem 4.126. What is the mass of the sample?
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Textbook Question
What is the molar concentration of As(III) in a solution if 22.35 mL of 0.100 M KBrO3 is needed for complete reaction with 50.00 mL of the As(III) solution? The balanced equation is:
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Textbook Question
Standardized solutions of KBrO3 are frequently used in redox titrations. The necessary solution can be made by dissolving KBrO3 in water and then titrating it with an As(III) solution. What is the molar concentration of a KBrO3 solution if 28.55 mL of the solution is needed to titrate 1.550 g of As2O3? See Problem 4.128 for the balanced equation. (As2O3 dissolves in aqueous acid solution to yield H3AsO3: As2O3 + 3 H2OS 2 H3AsO3.)
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Textbook Question
The concentration of the Sn2+ solution used in Problem 4.130 can be found by letting it react with a known amount of Fe2+. What is the molar concentration of an Sn2+ solution if 23.84 mL is required for complete reaction with 1.4855 g of Fe2O3?
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Textbook Question
Alcohol levels in blood can be determined by a redox reaction with potassium dichromate according to the balanced equation What is the blood alcohol level in mass percent if 8.76 mL of 0.049 88 M K2Cr2O7 is required for complete reaction with a 10.002 g sample of blood?
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Textbook Question
Calcium levels in blood can be determined by adding oxa-late ion to precipitate calcium oxalate, CaC2O4, followed by dissolving the precipitate in aqueous acid and titrating the resulting oxalic acid (H2C2O4) with KMnO4: How many milligrams of Ca2+ are present in 10.0 mL of blood if 21.08 mL of 0.000 988 M KMnO4 solution is needed for the titration?
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