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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 104b

How many milliliters of 1.00 M KOH must be added to neutralize the following solutions? (b) A mixture of 0.300 M HCl (45.0 mL) and 0.250 M NaOH (10.0 mL)

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Neutralization Reaction

A neutralization reaction occurs when an acid reacts with a base to produce water and a salt. In this case, hydrochloric acid (HCl) and potassium hydroxide (KOH) will react to form water and potassium chloride (KCl). Understanding the stoichiometry of this reaction is essential for calculating the amounts of reactants needed for complete neutralization.
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Molarity and Volume Calculations

Molarity (M) is a measure of concentration defined as moles of solute per liter of solution. To find the number of moles of HCl and NaOH in the mixture, we can use the formula: moles = molarity × volume (in liters). This calculation is crucial for determining how much KOH is required to neutralize the total moles of acid present.
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Stoichiometry

Stoichiometry involves the calculation of reactants and products in chemical reactions based on balanced equations. For the neutralization of HCl by KOH, the balanced equation shows a 1:1 molar ratio. This means that the moles of KOH needed will equal the moles of HCl after accounting for any NaOH present, allowing for accurate determination of the volume of KOH required.
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