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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 149b

(b) When 5.00 g of X is titrated with NaOH, it is found that X has two acidic hydrogens that react with NaOH and that 54.9 mL of 1.00 M NaOH is required to completely neu-tralize the sample. What is the molecular formula of X?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Titration

Titration is a quantitative analytical technique used to determine the concentration of a solute in a solution. In this process, a solution of known concentration (the titrant, here NaOH) is gradually added to a solution of the analyte (substance X) until the reaction reaches completion, indicated by a color change or a specific endpoint. The volume of titrant used allows for calculations to determine the amount of the analyte present.
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Acidic Hydrogens

Acidic hydrogens are hydrogen atoms in a molecule that can be released as protons (H+) in a reaction, typically with a base. The presence of two acidic hydrogens in the compound X indicates that it can donate two protons during the neutralization reaction with NaOH. This information is crucial for determining the stoichiometry of the reaction and ultimately the molecular formula of the compound.
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Molecular Formula Calculation

The molecular formula of a compound represents the number and type of atoms present in a molecule. To determine the molecular formula of X, one must use the data from the titration, including the mass of X and the volume and concentration of NaOH used. By calculating the moles of NaOH reacted and relating it to the moles of acidic hydrogens in X, one can derive the empirical formula and subsequently the molecular formula.
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Related Practice
Textbook Question
A mixture of FeCl2 and NaCl is dissolved in water, and addi-tion of aqueous silver nitrate then yields 7.0149 g of a pre-cipitate. When an identical amount of the mixture is titrated with MnO4 -, 14.28 mL of 0.198 M KMnO4 is needed for complete reaction. What are the mass percents of the two compounds in the mixture? (Na+ and Cl-do not react with MnO4 -. The equation for the reaction of Fe2+ with MnO4 was given in Problem 4.146.)
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Textbook Question
Salicylic acid, used in the manufacture of aspirin, contains only the elements C, H, and O and has only one acidic hydrogen that reacts with NaOH. When 1.00 g of salicylic acid undergoes complete combustion, 2.23 g CO2 and 0.39 g H2O are obtained. When 1.00 g of salicylic acid is titrated with 0.100 M NaOH, 72.4 mL of base is needed for complete reaction. What are the empirical and molecular formulas of salicylic acid?
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Textbook Question

Compound X contains only the elements C, H, O, and S. A 5.00 g sample undergoes complete combustion to give 4.83 g of CO2, 1.48 g of H2O, and a certain amount of SO2 that is further oxidized to SO3 and dissolved in water to form sulfuric acid, H2SO4. On titration of the H2SO4, 109.8 mL of 1.00 M NaOH is needed for complete reaction. (Both H atoms in sulfuric acid are acidic and react with NaOH.) (a) What is the empirical formula of X?

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Textbook Question

A 1.268 g sample of a metal carbonate (MCO3) was treated with 100.00 mL of 0.1083 M sulfuric acid (H2SO4), yielding CO2 gas and an aqueous solution of the metal sulfate (MSO4). The solution was boiled to remove all the dissolved CO2 and was then titrated with 0.1241 M NaOH. A 71.02 mL volume of NaOH was required to neutralize the excess H2SO4. (a) What is the identity of the metal M?

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Textbook Question

(b) How many liters of CO2 gas were produced if the density of CO2 is 1.799 g/L?

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Textbook Question

Element M is prepared industrially by a two-step procedure according to the following (unbalanced) equations:

Assume that 0.855 g of M2O3 is submitted to the reaction sequence. When the HCl produced in step (2) is dissolved in water and titrated with 0.511 M NaOH, 144.2 mL of the NaOH solution is required to neutralize the HCl. (a) Balance both equations.

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