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Ch.3 - Mass Relationships in Chemical Reactions
Chapter 3, Problem 110

Assume that gasoline has the formula C8H18 and has a density of 0.703 g/mL. How many pounds of CO2 are produced from the complete combustion of 1.00 gal of gasoline?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Combustion Reaction

A combustion reaction is a chemical process in which a substance reacts with oxygen to produce heat and light. In the case of hydrocarbons like gasoline (C8H18), complete combustion yields carbon dioxide (CO2) and water (H2O). Understanding the stoichiometry of this reaction is essential for calculating the amount of CO2 produced from a given quantity of gasoline.
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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced chemical equation. It allows us to determine the relationships between the quantities of substances involved. For the combustion of C8H18, knowing the molar ratios from the balanced equation is crucial for converting the amount of gasoline into the corresponding amount of CO2 produced.
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Density and Volume Conversion

Density is defined as mass per unit volume and is crucial for converting between volume and mass. In this problem, the density of gasoline (0.703 g/mL) allows us to convert the volume of gasoline (1.00 gal) into grams. This conversion is necessary to relate the mass of gasoline to the amount of CO2 produced through stoichiometric calculations.
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Related Practice
Textbook Question

b) Given the mass spectrum of benzene, identify the molecular weight and give the molecular formula.

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Textbook Question
(a) Combustion analysis of 150.0 mg of 1,2,3,benzenetriol, a compound composed of carbon, hydrogen, and oxy-gen, gives 64.3 mg of H2O and 314.2 mg of CO2. What is the empirical formula of 1,2,3,benzenetriol?
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Textbook Question

The molecular weight of ethylene glycol is 62.0689 when calculated using the atomic weights found in a standard periodic table, yet the molecular weight determined experimentally by high-resolution mass spectrometry is 62.0368. Explain the discrepancy.

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Textbook Question
Compound X contains only carbon, hydrogen, nitrogen, and chlorine. When 1.00 g of X is dissolved in water and allowed to react with excess silver nitrate, AgNO3, all the chlorine in X reacts and 1.95 g of solid AgCl is formed. When 1.00 g of X undergoes complete combustion, 0.900 g of CO2 and 0.735 g of H2O are formed. What is the empirical formula of X?
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Textbook Question
A pulverized rock sample believed to be pure calcium carbonate, CaCO3, is subjected to chemical analysis and found to contain 51.3% Ca, 7.7% C, and 41.0% O by mass. Why can't this rock sample be pure CaCO3?
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Textbook Question
A certain alcoholic beverage contains only ethanol (C2H6O) and water. When a sample of this beverage undergoes com-bustion, the ethanol burns but the water simply evaporates and is collected along with the water produced by combus-tion. The combustion reaction is When a 10.00 g sample of this beverage is burned, 11.27 g of water is collected. What is the mass in grams of ethanol, and what is the mass of water in the original sample?
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