Ch.3 - Mass Relationships in Chemical Reactions
Chapter 3, Problem 107
(a) Combustion analysis of 150.0 mg of 1,2,3,benzenetriol, a compound composed of carbon, hydrogen, and oxy-gen, gives 64.3 mg of H2O and 314.2 mg of CO2. What is the empirical formula of 1,2,3,benzenetriol?
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Textbook Question
The molecular weight of an organic compound was found by mass spectrometry to be 70.042 11. Is the sample C5H10, C4H6O, or C3H6N2? Exact masses of elements are: 1.007 825 (1H); 12.000 00 (12C); 14.003 074 (14N); 15.994 915 (16O).
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Textbook Question
(a) Combustion analysis of 50.0 mg of benzene, a commonly used solvent composed of carbon and hydrogen, gives 34.6 mg of H2O and 169.2 mg of CO2. What is the empirical formula of benzene?
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Textbook Question
b) Given the mass spectrum of benzene, identify the molecular weight and give the molecular formula.
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Textbook Question
The molecular weight of ethylene glycol is 62.0689 when calculated using the atomic weights found in a standard periodic table, yet the molecular weight determined experimentally by high-resolution mass spectrometry is 62.0368. Explain the discrepancy.
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Textbook Question
Assume that gasoline has the formula C8H18 and has a density of 0.703 g/mL. How many pounds of CO2 are produced from the complete combustion of 1.00 gal of gasoline?
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Textbook Question
Compound X contains only carbon, hydrogen, nitrogen, and chlorine. When 1.00 g of X is dissolved in water and allowed to react with excess silver nitrate, AgNO3, all the chlorine in X reacts and 1.95 g of solid AgCl is formed. When 1.00 g of X undergoes complete combustion, 0.900 g of CO2 and 0.735 g of H2O are formed. What is the empirical formula of X?
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