Chapter 21, Problem 83b
Write the formula for each of the following compounds.
(c) Hexacarbonylmolybdenum(0)
(d) Diamminebis(ethylenediamine)chromium(III) chloride
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Write the formula for each of the following compounds.
(a) Tetraammineplatinum(II) chloride
(b) Sodium hexacyanoferrate(III)
Write the formula for each of the following compounds.
(c) Tris(ethylenediamine)platinum(IV) sulfate
(d) Triamminetrithiocyanatorhodium(III)
Write the formula for each of the following compounds.
(a) Diamminesilver(I) nitrate
(b) Potassium diaquadioxalatocobaltate(III)
Which of the following complexes are chiral?
(a) Pt(en)Cl2
(b) cis-[Co(NH3)4Br2]+
(c) cis-[Cr(en)2(H2O)2]3+
(d) [Cr(C2O4)3]3-
Tris(2-aminoethyl)amine, abbreviated tren, is the tetradentate ligand N(CH2CH2NH2)3. Using to represent each of the three NCH2CH2NH2 segments of the ligand, sketch all possible isomers of the octahedral complex [Co(tren)BrCl]+.
Consider the octahedral complex [Co(en)(dien)Cl]2+, where dien = H2NCH2CH2NHCH2CH2NH2, which can be abbreivated
(a) The dien (diethylenetriamine) ligand is a tridentate ligand. Explain what is meant by 'tridentate' and why dien can act as a tridentate ligand.
(b) Draw all possible stereoisomers of [Co(en)(dien)Cl]2+ (dien is a flexible ligand). Which stereoisomers are chiral, and which are achiral?