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Ch.20 - Nuclear Chemistry
Chapter 20, Problem 74

Why does a given nucleus have less mass than the sum of its constituent protons and neutrons?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Mass Defect

The mass defect refers to the difference between the mass of an atomic nucleus and the sum of the masses of its individual protons and neutrons. This phenomenon occurs because when nucleons (protons and neutrons) bind together to form a nucleus, some of their mass is converted into energy, as described by Einstein's equation E=mc². This energy is released during the formation of the nucleus, resulting in a lower overall mass.
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Binding Energy

Binding energy is the energy required to disassemble a nucleus into its individual protons and neutrons. It is a measure of the stability of the nucleus; a higher binding energy indicates a more stable nucleus. The binding energy is directly related to the mass defect, as the energy released during nucleon binding accounts for the mass that is 'lost' when the nucleus is formed.
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Nuclear Forces

Nuclear forces are the strong interactions that hold protons and neutrons together within the nucleus. These forces are much stronger than the electromagnetic forces that would otherwise cause protons to repel each other due to their positive charge. The strong nuclear force operates at very short ranges and is responsible for the stability of the nucleus, contributing to the mass defect and binding energy.
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Related Practice
Textbook Question
The electronic systems on the New Horizons spacecraft, which launched on January 19, 2006, and reached its closest approach to Pluto on July 14, 2015, were powered by elec-tricity generated by heat. The heat came from the radioac-tive decay of 238Pu in the 11 kg of 238PuO2 fuel onboard. The generator provided 240 W when the spacecraft was launched. If the power output is directly proportional to the amount of 238Pu in the generator, what was the power output when the spacecraft reached Pluto? The half-life of 238Pu is 87.7 y.
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Textbook Question
Uranium-238 has a half-life of 4.47 * 109 years and decays through a series of events to yield lead-206. Estimate the age of a rock that contains 105 mmol of 238U and 33 mmol of 206Pb. Assume all the 206Pb is from the decay of 238U.
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Textbook Question
The age of an igneous rock that has solidified from magma can be found by analyzing the amount of 40K and 40Ar. Potassium-40 emits a positron to produce argon-40 and the half-life of 40K is 1.25 * 109 years. What is the age of a rock whose 40Ar/40K ratio is 1.42?
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Textbook Question
In an endothermic chemical reaction, do the products have more mass, less mass, or the same mass as the reactants? Explain.
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Textbook Question
Calculate the mass defect (in g/mol) and the binding energy (in MeV/nucleon) for the following nuclei. Which of the two is more stable? (a) 50Cr (atomic mass = 49.94605) (b) 64Zn (atomic mass = 63.92915)
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Textbook Question
Calculate the mass defect (in g/mol) and the binding energy (in MeV/nucleon) for the following nuclei. Which of the two is more stable? (a) 7Li (atomic mass = 7.016004) (b) 39K (atomic mass = 38.963706)
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