Chapter 18, Problem 27b
Ideal gases A (red spheres) and B (blue spheres) occupy two separate bulbs. The contents of both bulbs constitute the initial state of an isolated system. Consider the process that occurs when the stopcock is opened.
(b) What are the signs ( + , - , or 0) of ∆H, ∆S, and ∆G for this process? Explain.
Video transcript
Formation constants for the ammonia and ethylenediamine complexes of nickel(II) indicate that Ni(en)32+ is much more
stable than Ni(NH3)62+:
(1) <REACTION>
(2) <REACTION>
The enthalpy changes for the two reactions, ΔH°1 and ΔH°2, should be about the same because both complexes have six Ni﹣N bonds.
(c) Assuming that ΔH°2 - ΔH°1 is zero, calculate the value of ΔS°2 - ΔS°1.
Ideal gases A (red spheres) and B (blue spheres) occupy two separate bulbs. The contents of both bulbs constitute the initial state of an isolated system. Consider the process that occurs when the stopcock is opened.
(a) Sketch the final (equilibrium) state of the system.
Ideal gases A (red spheres) and B (blue spheres) occupy two separate bulbs. The contents of both bulbs constitute the initial state of an isolated system. Consider the process that occurs when the stopcock is opened.
(c) How dpes this process illustrate the second law of thermodynamics?
Ideal gases A (red spheres) and B (blue spheres) occupy two separate bulbs. The contents of both bulbs constitute the initial state of an isolated system. Consider the process that occurs when the stopcock is opened.
(d) Relate each of the pictures to the graph in Figure 18.11.