Skip to main content
Ch.18 - Thermodynamics: Entropy, Free Energy & Equilibrium

Chapter 18, Problem 27b

Ideal gases A (red spheres) and B (blue spheres) occupy two separate bulbs. The contents of both bulbs constitute the initial state of an isolated system. Consider the process that occurs when the stopcock is opened.

(b) What are the signs ( + , - , or 0) of ∆H, ∆S, and ∆G for this process? Explain.

Verified Solution
Video duration:
1m
This video solution was recommended by our tutors as helpful for the problem above.
279
views
Was this helpful?

Video transcript

Hello everyone today. We have the following problem. Three vessels were occupied by ideal gasses, X. For the gray spheres, Y. For the yellow spheres and Z for the green spheres separately. The contents of the vessels represent the original state of an isolated system. When the stop cocks are open, determine the signs positive, negative and zero of our changing our change in entropy and are changing gibbs free energy for the process that occurs. So when the stop clocks are opened, these ideal gasses are going to mix together and so for the mixing of ideal gasses, there is essentially no heat that is gained or lost during the process and therefore our change in our entropy is going to equal zero. Furthermore, when we mix these ideal gasses, it's going to increase the disorder in the system. Therefore our changing our entropy is going to be greater than zero or it's going to have a positive sign. And lastly mixing these ideal gasses is a spontaneous process and therefore our change in our gifts. Free energy is going to be less than zero or have a negative sign. And so with that we have our answer overall, I hope this helped. And until next time
Related Practice
Textbook Question

Formation constants for the ammonia and ethylenediamine complexes of nickel(II) indicate that Ni(en)32+ is much more

stable than Ni(NH3)62+:

(1) <REACTION>

(2) <REACTION>

The enthalpy changes for the two reactions, ΔH°1 and ΔH°2, should be about the same because both complexes have six Ni﹣N bonds. 

(c) Assuming that ΔH°2 - ΔH°1 is zero, calculate the value of ΔS°2 - ΔS°1.

100
views
Textbook Question
Consider the gas-phase reaction of AB3 and A2 molecules:

(a) Write a balanced equation for the reaction. (b) What is the sign of the entropy change for the reaction?
796
views
Textbook Question

Ideal gases A (red spheres) and B (blue spheres) occupy two separate bulbs. The contents of both bulbs constitute the initial state of an isolated system. Consider the process that occurs when the stopcock is opened.

(a) Sketch the final (equilibrium) state of the system.

262
views
Textbook Question

Ideal gases A (red spheres) and B (blue spheres) occupy two separate bulbs. The contents of both bulbs constitute the initial state of an isolated system. Consider the process that occurs when the stopcock is opened.

(c) How dpes this process illustrate the second law of thermodynamics?

326
views
Textbook Question

Ideal gases A (red spheres) and B (blue spheres) occupy two separate bulbs. The contents of both bulbs constitute the initial state of an isolated system. Consider the process that occurs when the stopcock is opened.

(d) Relate each of the pictures to the graph in Figure 18.11.

326
views
Textbook Question
Rank the situations represented by the following drawings according to increasing entropy.
326
views