Ch.17 - Applications of Aqueous Equilibria
Chapter 17, Problem 122
Write a balanced net ionic equation for each of the follow-ing dissolution reactions, and use the appropriate Ksp and Kf values in Appendix C to calculate the equilibrium constant for each. (b) Cu(OH)2 in aqueous NH3 to form [Cu(NH3)4]2+
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Related Practice
Textbook Question
Is the solubility of Fe(OH)3 increased, decreased, or unchanged on addition of each of the following substances? Write a balanced net ionic equation for each dissolution reaction. (See Appendix C.6 for formulas of complex ions.)
(b) NaOH(aq)
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Textbook Question
Dissolution of 5.0 x 10^-3 mol of Cr(OH)3 in 1.0 L of 1.0 M NaOH gives a solution of the complex ion [Cr(OH)4]- (Kf = 8 x10^29). What fraction of the chromium in such a solution is present as uncomplexed Cr3+?
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Textbook Question
Write a balanced net ionic equation for each of the follow-ing dissolution reactions, and use the appropriate Ksp and Kf values in Appendix C to calculate the equilibrium constant for each.
(a) AgI in aqueous NaCN to form [Ag(CN)2]-
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Textbook Question
Calculate the molar solubility of AgI in:
(a) Pure Water
(b) 0.10 M NaCN: Kf for [Ag(CN)2]- is 3.0 x 10^20
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Textbook Question
Calculate the molar solubility of Cr(OH)3 in 0.50 M NaOH; Kf for Cr(OH)4- is 8 x 10^29.
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Textbook Question
Citric acid (H3Cit) can be used as a household cleaning agent to dissolve rust stains. The rust, represented as Fe(OH)3, dissolves because the citrate ion forms a soluble complex with Fe3+
(a) Using the equilibrium constants in Appendix C and Kf = 6.3 x 10^11 for Fe(Cit), calculate the equilibrium constant K for the reaction.
(b) Calculate the molar solubility of Fe(OH)3 in 0.500 M solution of H3Cit.
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